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TEA^+-TMA^+-SiO_2-Al_2O_3-H_2O体系下影响UZM-5分子筛自发结晶的因素 被引量:2

Effect Factors on Synthesis of UZM-5 Molecular Sieves in the System of TEA^+-TMA^+-SiO_2-Al_2O_3-H_2O
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摘要 研究了 TEA^+-TMA^+-SiO_2-Al_2O_3-H_2O 体系下 UZM-5分子筛自发结晶过程,考察了晶化时间、晶化温度、模板剂用量、H_2O 和硅铝比对 UZM-5分子筛结晶过程的影响。结果表明,当合成体系中TEA^+与 SiO_2物质的量之比为0.6~1.0,TMA^+与 SiO_2物质的量之比为0.075~0.125,H_2O 与 TEA^+物质的量之比为31.2和 Si 与 Al 物质的量之比为6~10的条件下,UZM-5分子筛能自发结晶。高温不利于UZM-5分子筛的形成,而低温则需要较长的晶化时间才能得到 UZM-5分子筛。在 SiO_2,Al_2O_3,TEAOH,TMACl 和 H_2O 物质的量之比为1.0:0.062 5:0.8:0.100:24.8时合成 UZM-5分子筛,在晶化温度150℃和晶化时间60 h 的条件下,合成的 UZM-5分子筛,其外表面较大,适合作较大有机分子反应的催化材料。 The spontaneous crystallization of UZM-5 molecular sieves was sudied in the reaction system of TEA^+-TMA^+-SiO2-Al2O3-H2O under different crystallization conditions. The effects of crystallization temperature, crystallization time, dosage of TEAOH and TMAC1, H2O content and molar ratio of Si to Al on the process of crystallization were investigated. The results showed that pure phase of UZM-5 crystallized spontaneously under the conditions of molar ratio of TEA^+ to SiO2 0.6-1.0, molar ratio of TMA^+ to SiO2 0.075-0.125, molar ratio of H2O to TEA^+ 31.2 and molar ratio of Si to Al 6-10. High temperature was not suitable for crystallization of UZM-5 molecular sieves, while low temperature was suitable for crystallization of UZM-5 molecular sieves but long time needed. Under the conditions of molar ratio of SiO2, Al2O3, TEAOH and TMAC1 to H2O was 1.0 : 0. 062 5 : 0.8: 0. 100:24.8, crystallization temperature 150℃ and crystallization time 60 h, the synthesized UZM-5 molecular sieves had large external surface and was suitable catalyst material for big organic molecules.
出处 《化学反应工程与工艺》 EI CAS CSCD 北大核心 2008年第4期353-357,共5页 Chemical Reaction Engineering and Technology
基金 973项目(2003CB615800)
关键词 UZM-5分子筛 模板作用 四甲基氯化铵 四乙基氢氧化铵 UZM-5 molecular sieves templating tetraethylammonium tetramethylammonium
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参考文献7

  • 1Tanable K, Holderich W F. Industrial Application of Solid Acid-Base Catalysts. Applied Catalysis A: General, 1999, 181 (2) : 399-434
  • 2Corma A, Diaz U, Domine M E, et al. New Aluminosilicate and Titanosilicate Delaminated Materials Active for Acid Catalysis, and Oxidation Reactions Using H2O2. J Am Chem Soc, 2000, 122 (12) : 2804-2809
  • 3Blackwell C S, Broach R W, Gatter M G, et al. Open-Framework Materials Synthesized in TEA^+/TMA^+ Mixed-Template System: the New Low Si/Al Ratio Zeolite UZM-4 and UZM-5. Angew Chem Int Ed, 2003, 42 (15) : 1737-1740
  • 4谢在库,钱斌,杨为民等.用于烷基芳烃异构化的催化剂.中国,CN200710040698.2007
  • 5Jan D Y, Lewis G J, Moscoso J G, et al. Aromatic Alkylation Process Using UZM-5 and UZM-6 Aluminosilicates. USA,US 6500998. 2002
  • 6钱斌,贾银娟,王仰东等.用于醇类脱水制烯烃的催化剂.中国,CN200810032923.2008
  • 7Moscoso J G, Lewis G J, Miller M A, et al. UZM-5 UZM-5P and UZM-6: Crystalline Aluminosilicate Zeolites and Processes Using the Same. USA, US 6613302. 2003

同被引文献22

  • 1Corma A, Fornes V, Guil J M, et al. Preparation, Characterisation and Catalytic Actalytic Activity of ITQ-2, a Delaminated Zeolite[J]. Microporous Mesoporous Mater,2000, 38 ( 2 - 3 ) : 301 - 309.
  • 2Corma A, Fornes V, Pergher S B, et al. Delaminated Zeolite Precursors as Selective Acidic Catalysts[ J]. Nature, 1998, 396(6709):353 -356.
  • 3Corma A, Diaz U, Domine M E, et al. AIlTQ-6 and TiITQ-6: Synthesis, Characterization, and Catalytic Activity [J ]. Angew Chem,Int Ed,2000, 29(8) :1499 - 1501.
  • 4Choi M, Na K, Kim J, et al. Stable Single-Unit-Cell Nanosheets of Zeolite MFI as Active and Long-Lived Catalysts[J]. Nature, 2009, 461 (7261) :246 - 249.
  • 5Zanardi S, Alberti A, Cruciani G, et al. Crystal Structure Deter- mination of Zeolite Nu-6 (2) and Its Layered Precursor Nu-6 ( 1 )[J]. Angew Chem,lnt Ed,2004, 43(37) :4933 -4937.
  • 6Corma A, Fornes V, Diaz U, ITQ-18 a New Delaminated Stable Zeolite[J].Chem Commun,2001, ( 24 ) :2642 - 2643.
  • 7Zubowa H L, Schneider M, Schreier E, et al. The Influence of the Expanding and Exfoliating Conditions on the Structural Transformation of the Layered Zeolite Nu-6 ( 1 ) [ J ]. Microporous Mesoporous Mater,2008, 109( 1 - 3 ) :317 - 326.
  • 8Blackwell C S, Broach R W, Gatter M G, et al. Open-Framework Materials Synthesized in the TMA +/TEA + Mixed-Template System: The New Low Si/A1 Ratio Zeolites UZM-4 and UZM-5[J]. Angew Chem, Int Ed,2003, 42 ( 15 ) : 1737 - 1740.
  • 9Corma A, Fornes V, Martinez-Triguero J, et al. Delaminated Zeolites: Combining the Benefits of Zeolites and Mesoporous Materials for Catalytic Uses[J]. J Catal, 1999, 186( 1 ) :57 - 63.
  • 10Corma A, Diaz A, Domine M E, et al. New Aluminosilicate and Titanosilicate Delaminated Materials Active for Acid Catalysis, and Oxidation Reaction Using H2 O2 [J]. J Am Chem Soc, 2000, 122 (12) :2804 - 2809.

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