摘要
采用交流阻抗谱技术,研究了以共轭聚合物(poly[2-methoxy,5-(2′-ethylhexoxy)-1,4-phenylenevinylene])(MEH-PPV)为发光层,以带有胺基的聚芴共聚物poly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)](PF-NR2)为电子传输层的发光二极管的交流响应特性.对于结构为ITO/PEDOT/MEH-PPV/PF-NR2/Al的发光器件,交流阻抗谱中出现了负电容效应(negative capacitance),根据对其Cole-Cole图的分析,MEH-PPV/PF-NR2界面的交流响应可用一个RLL并联电路来模拟,实验结果表明,PF-NR2层既是电子传输层同时又充当了空穴阻挡层的作用,并给出了解释这种以PF-NR2/Al为阴极的器件效率提高的微观机理.
A.c. electrical properties of the heterostructured polymer light-emitting diode consisting of poly[ 2-methoxy-5-(2'-ethyl- hexyloxy)- 1, 4-phenylenevinylene ] ( MEH- PPV) as the light-emitting layer, and poly [ ( 9,9 - bis ( 3'- ( N, N- dimethylamino) propyl)-2, 7- fluorene )-alt-2, 7-( 9, 9-dioctylfluorene ) ] ( PF-NR2 ) as the electron-injecting layer, are studied by using impedance spectroscopy. Negative capacitance in impedance spectroscopic data has been observed. According to the Cole-Cole plot of the device ITO/PEDOT/MEH-PPV/PF-NR2/A1, the a.c. response of MEH-PPV/PF-NR2 interface can be explained in terms of the equivalent circuit model of a parallel combination of an inductance L and a resistance RL . The experiments showed that PF-NR2 could act as an electron injecting and hole blocking layer. We propose an energy band structure schematic diagram to explain the enhancement of the EL efficiency in the ITO/PEDOT/MEH-PPV/PF-NR2/Al structure.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
2008年第9期5983-5988,共6页
Acta Physica Sinica
基金
国家自然科学基金(批准号:90201031,50573024)
教育部科学技术研究重点项目(批准号:104208)
科技部“973”计划项目(批准号:2002CB61340205)资助的课题~~
关键词
PF-NR_2
聚合物发光二极管
交流阻抗谱
负电容效应
PF-NR2, polymer light-emitting diodes (PLEDs), impedance spectroscopy, negative capacitance (NC)