摘要
A new polyoxometalate comPOund formulated as Na2（C3H5N2）4[MnMo9O32]·2H2O 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group C2/c, with a = 16.076（2）, b = 14.6488（19）, c = 18.767（2）A ,β = 108.6030（10）°, V = 4188.6（9）A^3, C12H24MnMo9NsNa2O34, Mr = 1788.77, Dc = 2.837 g/cm^3,μ（MoKa） = 3.024 mm^-1, F（000） = 3396, Z = 4, the final R = 0.0270 and wR = 0.0605 for 3829 observed reflections （I 〉 2σ（I））.
A new polyoxometalate comPOund formulated as Na2（C3H5N2）4[MnMo9O32]·2H2O 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group C2/c, with a = 16.076（2）, b = 14.6488（19）, c = 18.767（2）A ,β = 108.6030（10）°, V = 4188.6（9）A^3, C12H24MnMo9NsNa2O34, Mr = 1788.77, Dc = 2.837 g/cm^3,μ（MoKa） = 3.024 mm^-1, F（000） = 3396, Z = 4, the final R = 0.0270 and wR = 0.0605 for 3829 observed reflections （I 〉 2σ（I））.
基金
the Natural Science Foundation of Jilin Province(No.2005103)
