摘要
The two title compounds [Cu(sdba)(py)2(H2O)]n·2n(py) 1 and [Cu(sdba)(phen)(H2O)]n 2 (H2sdba = 4,4′-sulfonyldibenzoic acid, py = pyridine, phen = 1,10-phenanthroline) have been synthesized and characterized by single-crystal structure determination, IR and TG analyses. Compound 1 crystallizes in orthorhombic, space group Pbcm with a = 5.9833(12), b = 22.333(5), c = 24.571(5)A, V = 3283.3(12) A^3, Z = 4, C34H30N4OTSCu, Mr = 702.22, Dc = 1.388 g/cm^3, F(000) = 1396,μ(MoKa) = 0.780 mm^-1, the final R = 0.0599 and wR = 0.1767 for 3416 observed reflections with I 〉 2σ(I). Compound 2 crystallizes in monoclinic, space group C2/c with a = 22.9549(4), b = 12.2443(3), c = 17.8687(4)A, β = 110.873(1)°, V = 4692.69(18)A^3, Z = 8, C26H18N2O7SCu, Mr = 566.02, Dc = 1.602 g/cm^3, F(000) = 2312,μ(MoKa) = 1.078 mm^-1, the final R =0.0697 and wR = 0.1330 for 3452 observed reflections with I 〉 2σ(I). In both structures, the Cu^Ⅱ metal centers adopt five-coordination in slightly distorted tetragonal pyramidal geometries, while the second N-donor ligands bond or chelate to Cun ions as the terminal moiety. The weak interactions extend the two structures into high-dimensional supramolecular coordination-polymers.
The two title compounds [Cu(sdba)(py)2(H2O)]n·2n(py) 1 and [Cu(sdba)(phen)(H2O)]n 2 (H2sdba = 4,4′-sulfonyldibenzoic acid, py = pyridine, phen = 1,10-phenanthroline) have been synthesized and characterized by single-crystal structure determination, IR and TG analyses. Compound 1 crystallizes in orthorhombic, space group Pbcm with a = 5.9833(12), b = 22.333(5), c = 24.571(5)A, V = 3283.3(12) A^3, Z = 4, C34H30N4OTSCu, Mr = 702.22, Dc = 1.388 g/cm^3, F(000) = 1396,μ(MoKa) = 0.780 mm^-1, the final R = 0.0599 and wR = 0.1767 for 3416 observed reflections with I 〉 2σ(I). Compound 2 crystallizes in monoclinic, space group C2/c with a = 22.9549(4), b = 12.2443(3), c = 17.8687(4)A, β = 110.873(1)°, V = 4692.69(18)A^3, Z = 8, C26H18N2O7SCu, Mr = 566.02, Dc = 1.602 g/cm^3, F(000) = 2312,μ(MoKa) = 1.078 mm^-1, the final R =0.0697 and wR = 0.1330 for 3452 observed reflections with I 〉 2σ(I). In both structures, the Cu^Ⅱ metal centers adopt five-coordination in slightly distorted tetragonal pyramidal geometries, while the second N-donor ligands bond or chelate to Cun ions as the terminal moiety. The weak interactions extend the two structures into high-dimensional supramolecular coordination-polymers.
基金
the National Natural Science Foundation of China
Natural Science Foundation of Fujian Province
the Key Project of the Chinese Academy of Sciences(No.2006F3130)