摘要
The title compound,α,α,β,β-5,10,15,20-tetrakis（2-aminophenyl）porphyrin, has been obtained and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2/c with a = 31.804（6）, b = 19.314（4）, c = 12.872（3） A, β= 90.592（3）°, Z = 4, V = 7907（3） A^3, Dc= 1.193 g/cm^3, Mr= 1419.67, λ（MoKα） = 0.71073A, μ= 0.073 mm^-1, F（000） = 2984, R = 0.0773 and wR = 0.2045. The crystallographic analysis indicates the existence of N-H...π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.
The title compound,α,α,β,β-5,10,15,20-tetrakis（2-aminophenyl）porphyrin, has been obtained and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2/c with a = 31.804（6）, b = 19.314（4）, c = 12.872（3） A, β= 90.592（3）°, Z = 4, V = 7907（3） A^3, Dc= 1.193 g/cm^3, Mr= 1419.67, λ（MoKα） = 0.71073A, μ= 0.073 mm^-1, F（000） = 2984, R = 0.0773 and wR = 0.2045. The crystallographic analysis indicates the existence of N-H...π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.
基金
the National Natural Science Foundation of China(No.20671053)
