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硒作用下苯胺和硫醇羰基化合成硫代氨基甲酸酯机理 被引量：1

Mechanism of Selenium-Mediated Carbonylation of Aniline with Thiols to Thiocarbamates
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摘要 通过具体的相关验证实验,并结合相关的文献报道,提出了硒作用下苯胺和硫醇羰基化合成硫代氨基甲酸酯的机理. On the basis of the results of the corresponding proof experiments and the report in literature, the mechanism of selenium-mediated carbonylation of aniline with thiols to thiocarhamates is proposed.
作者 张晓鹏 荆唤芝 苗江欢 陆世维
机构地区 河南师范大学化学与环境科学学院 中国科学院大连化学物理研究所
出处 《河南师范大学学报（自然科学版）》 CAS CSCD 北大核心 2008年第5期111-113,共3页 Journal of Henan Normal University(Natural Science Edition)
基金 河南省科技厅科技攻关资助项目(0624270005) 河南师范大学博士科研启动费支持课题
关键词 硒 苯胺 硫醇 羰基化 硫代氨基甲酸酯 机理 selenium aniline thiols carhonylation thlocarbamates mechanism
分类号 O621.1 [理学—有机化学]
  • 相关文献

参考文献6

  • 1Zhang X P,Lu S W. A new and facile route for the synthesis of thlocarbamates from aniline, carbon monoxide, and thiols mediated by selenium[J]. Chem Leu,2005,34(4) :606-607.
  • 2何建,张善言.芳香族硝基化合物还原碳基化合成二芳基脲[J].天然气化工—C1化学与化工,1994,19(4):26-29. 被引量：6
  • 3Sonoda N. Selenium assisted carbnnylation with carbon monoxide[J] Pure & Appl Chem, 1993,65 (4):699 -706.
  • 4Kondo K,Sonoda N.Tsutsumi S. A new synthesis of carbamates. The reaction of carbon monoxide with amine and alcohol in the co-presenceof selenium and triethylamine[J].Chem Lett,1972,1(5):373-374.
  • 5Stanley F B,Woodford S G. The occurrence of compounds of sulphur in the light distillate from the crude oil of maidan i naftun[J]. J Chem Soc,1925,127:905-908.
  • 6Donald G,Niemann C. Further studies on the synthesis of substituted ureas[J]. J Am Chem Soc,1954,76(17) :4458-4463.

共引文献5

同被引文献11

  • 1何建,张善言.芳香族硝基化合物还原碳基化合成二芳基脲[J].天然气化工—C1化学与化工,1994,19(4):26-29. 被引量：6
  • 2Zhang X P, Lu S W. A selenium-catalysed synthesis of thiocarbamates from nitroarenes, carbon monoxide and thiols under mild conditions [J]. J Chem Res,2008, (10) ,589-591.
  • 3Zhang X P,Lu S W. A novel one-pot solvent-free synthesis of thiocarbamates from nitroarenes, carbon monoxide and thiols assisted by triethylamine catalyzed by selenium[J].Synlett, 2005, (10) : 1535 - 1538.
  • 4Miyata T,Kondo K,Sonoda N,et al. Photoreduction of ketones and aldehydes to alcohols with hydron selenide[J].Angew Chem Int Ed Engl, 1980,19 : 1008-- 1009.
  • 5Sonoda N. Selenium assisted earbonylation with carbon monoxide[J].Pure & Appl Chem, 1993,65(4):699--706.
  • 6Liu X Z, Lu S W. Selective formation of aromatic amines by seleniun-catalyzed reduction of aromatic nitro compounds with CO/H2O under atmospheric pressure[J].J Mol Catal A:Chem,2004,212,127.
  • 7Kondo, K. Sonoda, N. Tsutsumi,S. A new synthesis of carbamates. The reaction of carbon monoxide with amine arid alcohol in the co - presence of selenium and triethylamine[J].Chem Lett, 1972,373-374.
  • 8Sonoda N, Yasuhara T,Kondo K,et al. A new synthesis of urea. The reaction of ammonia or aliphatic amines with carbon monoxide in the presence of selenium[J]. J Am Chem Soc, 1971,93(23):6344.
  • 9Kondo K,Sonoda N,Tsutsumi S. A new selenium-triethylamine catalysed synthesis of arylureas from carbon monoxide and aromatic amines[J].J Chem Soc Chem Comm, 1972,307-308.
  • 10徐应明,戴晓华,孙扬,林大松.硝基氯苯胁迫对小麦种子萌发和幼苗生长的影响[J].灌溉排水学报,2008,27(5):1-3. 被引量：4

引证文献1

河南师范大学学报（自然科学版）
2008年 第5期

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