摘要
A new polyoxometalate dimer based on lacunary Wells-Dawson anion and lanthanide cation, Na14[{Nd(H2O)3 (α2-PeWt7O61)2]·17H2O, was isolated as a sodium salt under ambient conditions and characterized by IR, TG, and X-ray single crystal structure analysis and electrochemistry. It belonged to the triclinic, space group Pi with a=1.26738 (15) nm, b=1.41464 (17) nm, c=2.3254 (4) nm, α=103.142 (2)°, β = 95.122 (2)°, γ=113.9690 (10)°, V=3.6317 (8)nm^3, Z=2, Dc=4.274 mg/m^3, and μ=27.695 mm^-1. The Nd^3+ ion was substituted for a [W=O]^4+ unit in the "cap" site of the tungsten-oxygen framework of the parent Wells-Dawson ion. The cyclic voltammograms of the title compound exhibited nearly chemically reversible one-step one-electron transfer process and two-step irreversible reduction processes. Thermogravimetric showed a one-step slow weight loss stage in the range of 25-850 ℃.
A new polyoxometalate dimer based on lacunary Wells-Dawson anion and lanthanide cation, Na14[{Nd(H2O)3 (α2-PeWt7O61)2]·17H2O, was isolated as a sodium salt under ambient conditions and characterized by IR, TG, and X-ray single crystal structure analysis and electrochemistry. It belonged to the triclinic, space group Pi with a=1.26738 (15) nm, b=1.41464 (17) nm, c=2.3254 (4) nm, α=103.142 (2)°, β = 95.122 (2)°, γ=113.9690 (10)°, V=3.6317 (8)nm^3, Z=2, Dc=4.274 mg/m^3, and μ=27.695 mm^-1. The Nd^3+ ion was substituted for a [W=O]^4+ unit in the "cap" site of the tungsten-oxygen framework of the parent Wells-Dawson ion. The cyclic voltammograms of the title compound exhibited nearly chemically reversible one-step one-electron transfer process and two-step irreversible reduction processes. Thermogravimetric showed a one-step slow weight loss stage in the range of 25-850 ℃.
基金
the Nature Science Foundation of Henan Province (0611011900)