摘要
用X—ray衍射和磁性测量的方法对所制备的La0.8Ce0.2Fe11.1-xCo0.8Si1.1Bx(x=0,0.3,0.6)的结构和磁性特征进行分析,发现B元素的添加不仅有利于该化合物形成单相NaZn13型晶体结构,且随B含量的增加样品居里温度由x=0.3的278K增加到x=0.6的286K,同时最大磁熵变|△SM(T)|也随之增大,在0~1.5T的磁场下由x=0.3的6.364J/kg·K增加到x=0.6的10.23J/kg·K.
The structural and magnetic properties of La0.8Ce0.2Fe11.1-xCo0.8Si1. 1Bx(x=0,0. 3, 0. 6) compound are investigated by means of X-ray diffraction and magnetization measurements. The results demonstrate that the addition of element B could help the compound to be crystallized in the cubic NaZn13-type structure. The Curie temperature Tc increases from 278 K for x=0. 3 to 286 K for x=0.6 with increasing B content. Simultaneity,the great magnetic entropy change |△SM(T)| also increases from 6. 364 J/kg · K for x=0. 3 to 10. 23 J/kg · K for x= 0. 6 under a field of 0-1.5 T with increasing B content.
出处
《内蒙古大学学报(自然科学版)》
CAS
CSCD
北大核心
2008年第5期526-530,共5页
Journal of Inner Mongolia University:Natural Science Edition
基金
国家自然科学基金资助项目(50164003)