摘要
One dimensional chain manganese(Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethyl-benzoic acid, 4,4'-bipyridine and manganese perchlorate anhydrous, and characterized by IR and elementary analysis. Its crystal belongs to orthorhombic space group Ccca with a=1.302 84(15) nm, b=2.601 1(3) nm, c=2.332 2(3) nm; V=7.903 5(15) nm3, Dc=1.227 g·cm-3, Z=8, F(000)=3 064, R1=0.068 4, wR2=0.210 9. The crystal structure shows that the manganese ion is coordinated with two nitrogen atoms of one 4,4'-bipyridine molecule and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 694096.
One dimensional chain manganese（Ⅱ） coordination polymer has been synthesized with 2,4,6-trimethylbenzoic acid, 4,4′-bipyridine and manganese perchlorate anhydrous, and characterized by IR and elementary analysis. Its crystal belongs to orthorhombic space group Ccca with a=1.302 84（15） nm, b=2.601 1（3） nm, c=2.3322（3） nm; V=7.903 5 （15） nm^3, Dc=1.227 g·cm^-3, Z=8, F（000）=3 064, R1=0.068 4, wR2=0.210 9. The crystal structure shows that the manganese ion is coordinated with two nitrogen atoms of one 4,4′-bipyridine molecule and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex shows that the electron transfer in electrode reaction is quasi-reversible. CCDC： 694096.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2008年第9期1510-1513,共4页
Chinese Journal of Inorganic Chemistry
基金
湖南省重点建设学科资助项目
湖南省教育厅基金资助(No06C195)
衡阳师范学院青年骨干项目(2006)
湖南工学院一般项目(NoHGY0731)
关键词
锰(Ⅱ)配合物
水热合成
晶体结构
电化学性质
manganese（Ⅱ）
hydrothermal synthesis
crystal structure
electrochemical property
