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13%过氧乙酸溶液热稳定性分析 被引量:5

Thermal stability of 13% acetic hydroperoxide
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摘要 13% Acetic hydroperoxide was investigated by accelerating rate calorimeter (ARC).From ARC test,the initial exothermic temperature was 45.25℃,the maximum pressure was 1.31 MPa,and the maximum self-heating rate temperature was 113.10℃.The measured results indicated that the acetic hydroperoxide was easy to decompose and had obvious explosive hazard.In the end,the paper discusses related prevention measures,such as cooling and reasonable relief method,to avoid hazard. 13% Acetic hydroperoxide was investigated by accelerating rate calorimeter (ARC) . From ARC test, the initial exothermic temperature was 45.25℃, the maximum pressure was 1.31 MPa, and the maximum self-heating rate temperature was 113.10℃. The measured results indicated that the acetic hydroperoxide was easy to decompose and had obvious explosive hazard, In the and the paper discusses related prevention measures, such as cooling and reasonable relief method, to avoid hazard.
出处 《化工学报》 EI CAS CSCD 北大核心 2008年第9期2260-2262,共3页 CIESC Journal
基金 河南省教育厅自然科学基金项目(2007620004)~~
关键词 过氧乙酸 绝热分解 加速量热仪 acetic hydroperoxide adiabatic decomposition accelerating rate calorimeter
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参考文献8

  • 1Townsend D I, Tou J C. Thermal hazard evaluation by an accelerating rate calorimeter. Thermochimica Acta, 1980, 37 : 1-30
  • 2Fu Zhimin(傅智敏).Evaluating thermal stability for reactive chemical by accelerating rate calorimeter [D]. Beijing: Beijing Institute of Technology, 2002
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二级参考文献16

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  • 8Fu Zhimin,Huang Jinyin,Ma Liang,Qian Xinming,Jiang Huiling.Investigation on thermal stability of five industrial explosives by adiabatic technique//Wang Yajun,Huang Ping,Li Shengcai.Theory and Practice of Energetic Materials.Beijing:Science Press,2003:251-255
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