三[(N-甲基-2-苯并咪唑)甲基]胺及其双铁核双桥配合物的合成和催化活性研究

Synthesis and Examination of Catalytic Activity for Tris [(N methy1 2 benzimidazol y1) methy 1] amine Coordinated with Iron to Form Binuclear Iron and Dibridged Complexes

用三角锥形四齿配体三［（Ｎ甲基２苯并咪唑）甲基］胺为配体，合成了甲烷单加氧酶的活性组分—羟基化酶的模型化合物。用叔丁基过氧化氢作氧化剂，研究了单加氧酶模型化合物对低碳烷烃和烯烃在温和条件下氧化的催化活性。实验结果表明，该模型化合物具有较高的催化活性。

The model complexes of hydroxylase, the active component of methane monooxyenase, were synthesized with tris [(N methy1 2 benzimidazol y1)methy1] amine corrdinated with iron to form binuclear iron complexes. The catalytic activity of model complexes was examinated for the oxidation of low hydro carbons with tert butylhydroperoxide under gentle condition. The results showed that the model complexes the high catalytic activity was high.