摘要
在氮气氛中采用配体取代法合成了C60以σ-π配位方式与Ru形成的稳定η2型富勒烯双核钌金属配合物(C60)2Ru2Cl4[Ph2P(CH2)4PPh2],其结构经UV,IR,XPS,XRD和元素分析表征。
A fullerene double core ruthenium metal η^2-complex {（C60）2Ru2Cl4[Ph2P（CH2）4PPh2]} with σ - π feedback pattern between C60 and Ru was synthesized by the method of ligand substituting in nitrogen atmosphere. The structure was characterized by UV, IR, XPS, XRD and elemental analysis.
出处
《合成化学》
CAS
CSCD
2008年第5期581-582,588,共3页
Chinese Journal of Synthetic Chemistry
基金
福建省自然科学基金资助项目(E04100001,E0110002)
关键词
钌
双核配合物
富勒烯
合成
ruthenium
double core complex
fullerene
synthesis
