摘要
The title complex,{[Cd2(1,8-nap)2(H2O)2](bpp)2}n(1) ,a cadmium complex based on mixed naphthalene-1,8-dicarboxylate(1,8-nap) and flexible 1,3-bi(4-pyridyl) propane(bpp) ligands,has been hydrothermally synthes-ized.It consists of a one-dimensional chain along c axis,which is derived from dimeric unit [Cd2(1,8-nap)2(H2O)2] linked by a pair of bpp ligands.In every [Cd2(1,8-nap)2(H2O)2] dimeric unit,two 1,8-nap act as bridging ligands to connect two Cd(Ⅱ) atoms,forming a sixteen-membered ring.Each Cd(Ⅱ) atom is in a distorted octahedral environment,coordinated by one aqua,two 1,8-nap and two bridging bpp ligands.In addition,two bridging bpp ligands connected two neighboring Cd(Ⅱ) atoms form a twenty-four-membered ring.The TGA and Luminescence property in solid state of complex 1 have been further studied and discussed in this paper.CCDC:669293.
The title complex,{[Cd2（1,8-nap）2（H2O）2]（bpp）2}n（1） ,a cadmium complex based on mixed naphthalene-1,8-dicarboxylate（1,8-nap） and flexible 1,3-bi（4-pyridyl） propane（bpp） ligands,has been hydrothermally synthes-ized.It consists of a one-dimensional chain along c axis,which is derived from dimeric unit [Cd2（1,8-nap）2（H2O）2] linked by a pair of bpp ligands.In every [Cd2（1,8-nap）2（H2O）2] dimeric unit,two 1,8-nap act as bridging ligands to connect two Cd（Ⅱ） atoms,forming a sixteen-membered ring.Each Cd（Ⅱ） atom is in a distorted octahedral environment,coordinated by one aqua,two 1,8-nap and two bridging bpp ligands.In addition,two bridging bpp ligands connected two neighboring Cd（Ⅱ） atoms form a twenty-four-membered ring.The TGA and Luminescence property in solid state of complex 1 have been further studied and discussed in this paper.CCDC：669293.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2008年第10期1713-1717,共5页
Chinese Journal of Inorganic Chemistry
基金
浙江省固体表面反应化学重点实验室开放基金资助项目(No.0506)。
关键词
镉(Ⅱ)配合物
晶体结构
荧光性质
cadmium（Ⅱ） complex
crystal structure
luminescence property
