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钴基费托合成催化剂活性及选择性影响因素分析 被引量:3

Analysis of the factors affecting the activity and selectivity of Co-based Fischer-Tropsch synthesis catalysts
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摘要 费托合成技术是一种重要的气变液(GTL)技术,其关键是研发高活性、高选择性、性能稳定、使用寿命长的催化剂。目前应用的费托合成催化剂主要有铁基和钴基催化剂两大类。钴基催化剂因其活性高,选择性好,性能稳定,受到越来越多的关注。本文介绍了钴基催化剂的特点和发展状况,分析了影响其活性和选择性的因素。 Fischer-Tropsch synthesis is one important technology for gas to liquid (GTL). The activity and selectivity of catalyst are key factors in this process. At present, there are mainly two kinds of catalysts, iron-based and cobalt-based, for it. The Co-based catalysts have attracted increasing attention due to their high activity, selectivity and performance stability. The characteristic and development of Co-based catalysts are reviewed, and the factors affecting the activity and selectivity of catalysts are analyzed.
出处 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2008年第5期66-71,共6页 Natural Gas Chemical Industry
关键词 费托合成 钴基催化剂 性能分析 影响因素 Fischer-Tropsch synthesis cobalt-based catalysts performance analysis influencing factors
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  • 1Yin D H,Li W H,Yang W S,et al.Mesoporous HMS Molecular Sieves Supported Cobalt Catalysts for Fischer-Tropsch Synthesis[J].Microporous Mesoporous Mater,2001,47:15.
  • 2Ducreux O, Lvnch J, Rebours B, et al. In situ characterisation of cobah based Fischer-Tropsch catalysts: A new approach to the active phase [J].Stud Surf Sci Catal,1998,119 (Nat Gas Cony Ⅴ): 125-130.
  • 3Kraum M,Baerns M. Fischer-Tropsch synthesis:The influence of various cobalt compounds applied in the preparation of supported cobalt catalysts on their performance[J] Appl Catal A, 1999,186(1-2): 189-200.
  • 4Niemela M K,Krause A O I,Vaara T,et al. The effect of the precursor on the characteristics of Co/SiO2 catalysts[J].Appl Catal A,1996,147(2):325-345.
  • 5Reuel R C, Bartholomew C H.Effect of support and dispersion on the CO hydrogenation activity/selectivity properties of cobalt[J].J Catal,1984,85:78-88.
  • 6侯朝鹏.氧化铝钴基F-T合成催化剂的改性研究[D].北京:中石化石油化工科学研究院,2005.
  • 7马文平,丁云杰,罗洪原,林励吾.浆态反应器中铁活性炭催化剂上还原研究[J].燃料化学学报,2001,29(4):375-377. 被引量:2
  • 8Bessell S. Support effects in Co-based FT catalysts[J].Appl Catal A, 1993, 96: 253-268.
  • 9Ernst B, Libs S, Chaumette P, et al. Preparation and charecterization of Fiseher-Tropsch active Co/SiO2 catalysts [J]. Appl Catal A,1999,186 (1-2):145-168.
  • 10Sun S , Fujimoto K, Zhang Y, et al. A highly active and stable Fischer-Tropsch synthesis cobalt/silica catalyst with bimodal cobalt particle distribution[J].Catal Commun ,2003, 4:361-364.

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