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Resonance-Enhanced Photon Excitation Spectroscopy of the Even-Parity Autoionizing Rydberg States of Xe

Resonance-Enhanced Photon Excitation Spectroscopy of the Even-Parity Autoionizing Rydberg States of Xe
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摘要 Xenon atoms were produced in their metastable states 5p^56s[3/2]2 and 5p^56s'[1/2]0 in a pulsed DC discharge in a beam, and subsequently excited to the even-parity autoionizing Rydberg states 5p^5np' [3/2] 1,[1/2] 1, and 5p^5nf' [5/2] 3 using single photon excitation. The excitation spectra of the even-parity autoionizing resonance series from the metastable 129Xe were obtained by recording the autoionized Xe+ with time-of-flight ion detection in the photon energy range of 28000-42000 cm-1. A wealth of autoionizing resonances were newly observed, from which more precise and systematic spectroscopic data of the level energies and quantum defects were derived.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第5期401-406,共6页 化学物理学报(英文)
基金 This work was supported by the National Natural Science Foundation of China (No.20673107), the Chinese National Key Basic Research Special Foundation (No.2007CB815203), and the Chinese Academy of Science (No.KJCX2-SW-H08).
关键词 XE Pulsed DC discharge Resonance-enhanced photon excitation spectroscopy Autoionizing resonance 共振增强 光子激发光谱 化学物理分析
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