摘要
用ReactIRIC10原位红外光谱仪实时监测了马来酸酐与十二醇的酯化反应过程,并对其动力学进行了研究。研究结果表明:在无催化剂存在条件下,82℃时反应1h,马来酸酐的转化率达到85.95%,酯化反应的反应级数为三级,反应活化能为95.01kJ/mol。
The kinetics of the esterification reaction processes between maleic anhydride and dodecanol were investigated with insitu FTIR technique. Under the chosen experimental conditions ( at the temperature of 82 ℃, 1 hour of reaction time, without any addition of catalyst), the conversation of maleie anhydride was 85.95% . The reaction was a third order reaction and apparent activation energy was 95.0 kJ/mol.
出处
《皮革与化工》
CAS
2008年第5期5-9,共5页
Leather And Chemicals
基金
山东省自主创新重大科技专项资助(2006GG1108097-10)