摘要
合成了酞菁铜[Cu(Ⅱ)Pc]及其衍生物四乙酰胺酞菁铜[Cu(Ⅱ)TcaPc]、四乙酸酞菁铜[Cu(Ⅱ)TcPc]、四吡啶并卟啉铜[Cu(Ⅱ)PTp]和四吡嗪并卟啉铜[Cu(Ⅱ)PTpz],并用元素分析法及红外光谱法进行了研究。通过恒电阻放电实验研究了它们对Li/SOCl2电池放电电压及时间的影响。结果表明:Cu(Ⅱ)PTp及Cu(Ⅱ)PTpz具有较好的催化活性。
Copper phthalocyanine[ Cu（ Ⅱ ） Pc] and its derivatives copper phthalocyanine-tetraacetamide [ Cu（ Ⅱ ） TcaPc], copper phthalocyanine-tetraearboxylic acid[ Cu（ Ⅱ ）TcPc], tetraeylpyridoporphyrin [ Cu（Ⅱ） PTp] and copper tetracylpyrazoporphyrin [ Cu （ Ⅱ ）PTpz] were synthesized and studied by elemental analysis and IR methods. Their effects on the discharge voltage and time of Li/SOCl2 battery were studied by constant resistance discharging test. The results showed that Cu（ Ⅱ ）PTp and Cu（ Ⅱ ）PTpz had better catalytic activity.
出处
《电池》
CAS
CSCD
北大核心
2008年第5期275-277,共3页
Battery Bimonthly
基金
国家自然科学基金(20671076)
