摘要
合成了Keggin结构一，三取代过氧铁钨硅杂多配合物，这两种化合物是：α－K6［SiW11（Tio2）O39］·12H2O和α－K9H［SiW9（TiO2）O39］·12H2O，并对183WNMR谱进行了指认，从而确定了2种过氧杂多配合物的基本结构．
In this paper heteropoly complexes of peroxotitanium mono-substituted and tri -substituted with Keggin structure: α- K5[SiW11(TiO2)O39·12H2O and α-K9H[SiW9(TiO3)O39· 12H2O Have been synthesized. The spectra of 183WNMR have been assigned so that two basic structures of peroxotitanium heteropoly complexes are determined.
