摘要
A new heterometallic 4f-3d complex [Y（C6NO2H5）3（H2O）2]n（1.5nZnCl4）·nH2O（1）, was synthesized via a hydrothermal reaction and structurally characterized. Complex 1 crystallized in the monoclinic system with space group P21/c： a=0.94847（9） nm, b=2.0947（2） nm, c=1.6001（2） nm, β=104.467（2）°, V=3.0781（5） nm3, Mr=823.04, Dc=1.776 g/cm3, S=1.009, μ（Mo Kα）=3.603 mm-1, F（000）=1632, R=0.0787, and wR=0.2273. Complex 1, with four formula units in a cell, was characteristic of a one-dimensional polycationic chain-like structure. Photoluminescent investigation showed that the title complex displayed a strong emission in the blue region, which was attributed to the intraligand π-π＊ transition of the nicotinic ligands. Optical absorption spectrum of complex 1 revealed the presence of a wide optical bandgap of 4.17 eV.
A new heterometallic 4f-3d complex [Y（C6NO2H5）3（H2O）2]n（1.5nZnCl4）·nH2O（1）, was synthesized via a hydrothermal reaction and structurally characterized. Complex 1 crystallized in the monoclinic system with space group P21/c： a=0.94847（9） nm, b=2.0947（2） nm, c=1.6001（2） nm, β=104.467（2）°, V=3.0781（5） nm3, Mr=823.04, Dc=1.776 g/cm3, S=1.009, μ（Mo Kα）=3.603 mm-1, F（000）=1632, R=0.0787, and wR=0.2273. Complex 1, with four formula units in a cell, was characteristic of a one-dimensional polycationic chain-like structure. Photoluminescent investigation showed that the title complex displayed a strong emission in the blue region, which was attributed to the intraligand π-π＊ transition of the nicotinic ligands. Optical absorption spectrum of complex 1 revealed the presence of a wide optical bandgap of 4.17 eV.
基金
the Natural Science Foundation of Jiangxi Province, China(No.200007GQH1685).
