摘要
以DMF为溶剂,合成不同n(NCO):n(OH)的聚氨酯(PU),将稀土钕盐掺入聚氨酯制得含稀土和高分子的复合材料。采用红外(FT-IR)、紫外—可见(UV-Vis)、差示扫描量热-热重分析(DSC- TGA)、荧光(FS)等手段对聚氨酯和复合材料进行了表征。红外光谱研究结果表明,钕离子与聚氨酯分子发生了作用;荧光光谱表明,复合材料发出钕的特征荧光,这为进一步研究稀土/高分子材料的性能提供了依据。
In the presence of N,N-dimethylformamide solvent,the polyurethanes with different mole ratio of NCO/OH (R) were synthesized. The composites containing rare earth and polymer were also prepared through rare earth Nd compound doping polyurethanes, The polyurethane and composites were characterized by infrared spectrum (FT-IR), differential scanning calorimeter (DSC), thermal gravimetric analysis (TGA),UV-Vis spectroscopy and fluorescence measurement. The results of FTIR showed that there existed interaction between Nd^3+ and polyurethane. The fluorescence spectrum indicated that the composites emitted the characteristic fluorescence of metal Nd,and this provided the basement for the property study of the rare earth element/polymer materials.
出处
《化工科技》
CAS
2008年第5期9-11,共3页
Science & Technology in Chemical Industry
基金
中国博士后科学基金资助项目(20070420973)
江苏省博士后科研资助计划项目(0602037B)
江苏大学高级人才基金资助项目(06JDG015和06JDG076)。
关键词
稀土
聚氨酯
荧光光谱
Rare-earth
Polyurethane
Fluorescence spectra