一种新型二茂铁丁酸混配合物的合成及晶体结构

Synthesis and crystal structure of a novel mixed-ligand complex from ferrocene

以二茂铁基丁酸(Fb)、4,4′-联吡啶(bpy)以及Zn(AC)2.2H2O为原料合成了一个新的混配合物Zn(Fb)2(bpy)2。X-射线单晶衍射分析表明,该化合物是一个四配体六配位单核配合物,并以氢键另连接两个二茂铁分子。

A novel mixed - ligand complex [ Zn （Fb） 2 （bpy） 2 ] ＂ 2 HFb （ Fb = 4 - ferroceny] butyrate aniont, bpy = 4, 4＇ - Bipyrine ） was obtained by the reaction of Zn（ Ac）2 · 2H20 with sodium 4 - ferrocenyl butyrate and 4,4＇ - Bipyrine in methanol solution. X - ray structural analysis reveals that it is a anisomerous uninuclear complex and in the compound both of 4 - ferrocenyl butyric acid connects the complex by hydrogen bond N -H.