3,3-二硝基氮杂环丁烷的Mannich反应研究

STUDY ON MANNICH REACTION OF 3,3DINITROAZETIDINE

３，３二硝基氮杂环丁烷分别与三硝基乙醇，２，２二硝基１，３丙二醇及１，１二硝基乙烷钾进行Ｍａｎｎｉｃｈ反应，合成了１（２′，２′，２′三硝基乙基）３，３二硝基氮杂环丁烷，１，３二（３′，３′二硝基氮杂环丁烷）２，２二硝基丙烷及１（３′，３′二硝基氮杂环丁烷）２，２二硝基丙烷。通过红外、核磁。

1(2′,2′,2′trinitroethyl)3,3dinitroazetidine, 1,3bi(3′,3′dinitroazetidine)2,,2dinitropropane and 1(3′,3′dinitroazetidine)2,2dinitropropane were synthesized by Mannich reaction of 3,3dinitroazetidine. Their molecular structures have been determined by elemental analysis, IR and 1H NMR spectra.