绝热式热动力学的研究——Ⅲ.二级反应的热谱解析

Studies on Adiabatic Thermokinetics Ⅲ. Thermokinetic Research of Second-Order Reactions

本文建立了二级反应在绝热系统中的热动力学研究法。并用自制的绝热式自动量热计,研究了几个放热反应体系的热动力学,而且对吸热反应体系的热动力学研究进行了探索。

An adiabatic thermokinetic research method of the second-order reactions is proposed in this paper The thermogram analysis of one endothermal reaction and three exothermal reactions have been undertaken with this method. The rate constants of these reactions calculated are in agreement with those reported in literatures. And the characteristics of this method have been disoussed in detail.