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稳定烯醇及其合成方法学 被引量:3

Stable Enols and Their Synthetic Methodologies
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摘要 烯醇受环境因素和取代基的影响在一定条件下可以稳定存在.研究稳定烯醇的结构特点、反应性质在有机化学理论研究和有机合成化学中有重要意义.从影响烯醇稳定的因素以及稳定烯醇合成方法学的角度对该领域进行了综述,分别讨论了芳基取代烯醇和脂肪基取代烯醇的稳定性及其合成方法. Enols can be stable or even isolable by beating special substituents or in proper environments. The study of structures and chemical behavior of stable enols is important from both theoretical and synthetic points of view. Here, the stabilities and synthetic methodologies of aromatic and aliphatic enols are discussed.
出处 《有机化学》 SCIE CAS CSCD 北大核心 2008年第11期1864-1874,共11页 Chinese Journal of Organic Chemistry
基金 国家自然科学基金(Nos.20632010 20521202 20702003)资助项目.
关键词 烯醇 稳定性 互变异构 合成 enol stability tautomerization synthesis
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