角度重叠模型中d轨道能量变化值的简化计算

Simple Calculation of d Orqital Energy Change Value in Angular Overlap Model

根据常见配合物的空间构型,求出了坐标系中几个基本位置配体的角度重叠因子S_λ~2,而其它配体(作为基本位置配体的等价配体)的S_λ~2值可由前者导出,简化了复杂的三角函数计算。

According to space Configuration of common coordination compounds,this paper find angular overlap factor S_λ~2 for a few basic place ligand in coordinate systems.Other ligand(egual value ligand of basic place ligand)S_λ~2 derive from above.It simplify complex calculations for triangular function.