摘要
氮化锡是一种新型薄膜锂电池负极材料,采用射频反应磁控溅射法制备氮化锡负极薄膜,系统研究了反应溅射功率和气流比对氮化锡薄膜结构的影响,并对其充放电性能进行了研究。实验结果表明,在溅射功率75W,N2/(N2+Ar)流量比0.5的条件下所制备氮化锡薄膜结晶度较好,表面致密具有良好的电性能,首次充放电效率超过60%,50次循环后放电比容量仍保持250mAh/g。
Tin nitride is a new kind of the negative electrode materials used for thin film lithium batteries. The tin nitride thin film was obtained by radio-frequency reactive magnetron sputtering methods. The influence of varying radio-frequency power and reactive gas composition on the structure of the tin nitride thin films was wholly investigated and the electrochemical performance of the films were also studied. The experiment results show that the tin nitride thin films prepared at RF power 75 W, N2/(N2+Ar) ratio 0.5, has high degree of crystallinity. And the tin nitride thin films has a compact surface and good electrochemistry performance: the first charge-discharge efficiency is over 60% and the specific discharge capacity for 50 cycles is 250 mAh/g.
出处
《电源技术》
CAS
CSCD
北大核心
2008年第11期742-744,747,共4页
Chinese Journal of Power Sources
关键词
薄膜锂电池
氮化锡
负极
反应溅射
thin film lithium battery
tin nitride
negative electrode
reactive sputtering