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304不锈钢在模拟循环冷却水中应力腐蚀破裂的临界Cl^-浓度 被引量:10

Critical Cl^- Concentration of Stress Corrossion Cracking for 304 Stainless Steel in Simulated Circular Cooling Water
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摘要 采用慢应变速率法和恒应变原位电化学测试法研究了304不锈钢在60℃的模拟循环冷却水中,氯离子对其耐蚀性能的影响。结果表明:Cl^-浓度小于600 mg/L时,随着Cl^-浓度的增加,膜破裂电位迅速负移,点蚀敏感性增大,未发生应力腐蚀破裂;Cl^-浓度大于600 mg/L时,随着Cl^-浓度的增加,膜破裂电位较负且变化缓慢,应力腐蚀破裂敏感性增大。 The effect of Cl^- on the corrosion resistance of 304 stainless steel in simulated circular cooling water at 60℃ was studied by means of in-situ electrochemical tests under constant strain condition and slow strain rate tests (SSRT). When Cl^- concentration was below 600 mg/L, the pitting potentials evolved towards negative sharply and the pitting corrosion susceptibility increased with the increase of Cl^- concentration; While above 600 mg/L, the pitting potentials shifted towardsnegative slowly and the stress corrosion cracking (SCC) susceptibility increased with the increase of Cl^- concentration.
出处 《腐蚀与防护》 CAS 北大核心 2008年第11期674-677,共4页 Corrosion & Protection
基金 中石化项目"三级炼油外排污水回用循环水成套技术开发"(306021)
关键词 304不锈钢 模拟循环冷却水 膜破裂电位 应力腐蚀破裂 临界Cl^-浓度 304 stainless steel simulated circular cooling water pitting potential SCC critical Cl^- concentration
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  • 1中华人民共和国水利部.2006年中国水资源公报[R].2007-09.
  • 2Cloet T E, Brozel V S, Von H A. Practical aspects of befouling control in industrial water system [J]. Int Biodet & Biodegad, 19 9 2,2 9 :2 9 9-- 3 41.
  • 3Marcus P. Surface science approach of corrosion phenomena[J]. Electrochemical Acta, 1988,43:109-- 118.

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