期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

硫杂杯[4]芳烃酰胺型氮杂冠醚的合成 被引量：1

Synthesis of Amide Thiacalix[4] crown
下载PDF
导出
摘要 硫杂杯[4]芳烃与N,N′-亚乙基双(2-氯乙酰胺)发生分子内"1+1"缩合反应,合成了新型硫杂杯[4]芳烃酰胺型氮杂冠醚——25,27-二羟基-26,28-(1,′10′-二氧杂-4,′7′-二氮杂-3,′8′-二氧代亚癸基)-硫杯[4]芳烃(叔丁基硫杯[4]-1,3-酰胺冠醚)(3),产率68%。1H NMR,ESI-MS和元素分析确证3为1,3-桥联模式且为杯式构象。 A novel amide thiacalix [ 4 ] crown, 25,27 -dihydroxy-26,28- （ 1＇, 10＇-dioxa4＇, 7＇-diaza-3＇, 8 ＇- dioxodecyl ） -thiacalix [ 4 ] arene （ p-tert-butylcalix [ 4 ] - 1,3 -amido-crown） （ 3 ） , in yield of 68 % was synthesized by ＂ 1 ＋ 1 ＂ condensation of thiacalix [ 4 ] arene with N, N＇-ethythlene-bi （ 2-chloracetamide）. 1,3-bridging structure and cone conformation of 3 was confirmed by 1H NMR, ESI-MS and elemental analysis.
作者 殷凤菊 杨发福 唐富胜 黄智胜
机构地区 福建师范大学化学与材料学院
出处 《合成化学》 CAS CSCD 2008年第6期664-665,669,共3页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(20402002) 福建省自然科学基金资助项目(2006J0155) 福建省高校新世纪优秀人才资助项目
关键词 硫杂杯[4]芳烃 冠醚 酰胺 合成 thiacalix[ 4 ] arene thiacalix [ 4 ] crown amide synthesis
分类号 O621.3 [理学—有机化学] O625.7 [理学—有机化学]
  • 相关文献

参考文献7

  • 1Lhotak P. Chemistry of thiacalixarenes[J]. Eur J Org Chem,2004,8 : 1675 - 1681.
  • 2胡晓钧,王丽,任杰,施宪法.硫杂杯芳烃——一类新型的分子受体化合物[J].化学通报,2004,67(2):90-95. 被引量：10
  • 3AGrtin A, Csokai V, Bitter I, et al. Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4] bis (crown) ethers [ J ]. Tetrabedron Lett,2002,43:4153 - 4156.
  • 4Leeuwen F W B, Beijleveld H,Reinhoudt D N, et al. Cation control on the synthesis of p-t-butylthiacalix[4] ( bis ) crownethers [ J ]. Tetrahedron Lett, 2002, 43 : 9675 - 9678.
  • 5Narumi F, Hattori T, Matsumura N, ToruOnodera, et al. Synthesis of an inherently chiral O, O-bridgedthiacalix[4] crowncarboxylic acid and its application to a chiral solvating agent [ J ]. Tetrahedron Lett, 2004,60: 7827 - 7833.
  • 6CsokaiV, Balazs B, Toth G, et al. Unprecedented cyclisations of calix[4] arenes under the Mitsunobu protocol. Part 3 : Thiacalix[ 4 ] crowns versus dimers [ J ]. Tetrahedron ,2004 ,60 : 12059 - 12066.
  • 7郭红玉,黄翠玉,杨发福,林建荣.选择性合成三取代乙氧羰基甲氧基硫杂杯[4]芳烃[J].合成化学,2008,16(4):440-441. 被引量：1

二级参考文献6

  • 1Lhotak P. Chemistry of thiacalixarenes [ J ]. Eur J Org Chem,2004,8 : 1675 - 1686.
  • 2St' astny, V, Stibor I, Petriekov6 H, et al. Thiaealix [4 ] arone derivatives with proximally bridged lower rim [ J ]. Tetrahedron, 2005,61:9990 - 9996.
  • 3Akdas H, Mislin G, Graf E, et al. Synthesis and solid state structural analysis of conformers of tetrakis [ ( ethoxycarbonyl ) methoxy ] tetrathiacalix [ 4 ] arene [ J ]. Tetrahedron Letters, 1999,40:2113 - 2116.
  • 4Iki N, Morohashi N, Narumi F, et al. Novel molecular receptors based on a thiacalix [ 4 ] arene platform. Preparations of the di- and tetracarboxylic acid derivatives and their binding properties towardstransition metal ions [ J ]. Tetrahedron Letters, 1999,40 : 7337 - 7340.
  • 5Chizuko Kabuto,Yutaka Higuchi,Tomohiro Niimi,Fumio Hamada,Nobuhiko Iki,Naoya Morohashi,Sotaro Miyano. Crystal Structures of Mono-, Di-, and Tri(p-tert-butyl)-thiacalixarenes: Dimeric Self-inclusion Behavior[J] 2002,Journal of Inclusion Phenomena and Macrocyclic Chemistry(1-2):89～98
  • 6胡旭波,韩鑫鑫,何家骐,黄海,程津培.一种制备带有酯基基团杯[4]芳烃的简便方法(英文)[J].合成化学,2000,8(2):151-154. 被引量：11

共引文献9

同被引文献10

  • 1杨发福,郑林禄,季衍卿,郭红玉,林建荣.含席夫碱和酰胺单元的新型双杯[4]芳烃的合成[J].有机化学,2006,26(2):268-270. 被引量：15
  • 2杨发福,赵夏,杨娥,郭红玉,黄翠玉.系列新型硫杂杯[4]芳烃氮杂衍生物的合成[J].有机化学,2007,27(5):670-673. 被引量：2
  • 3Tabakci M, Memon S, Yilmaz M, et al. Synthesis and evaluation of extraction ability of calix [ 4 ]-crown-6 cone conformer and its oligomeric analogue [ J ]. Peactive & Functional Polym ,2004,58 ( 1 ) :27 - 34.
  • 4Narumi F, Hattori T, Matsumura N, et al. Synthesis of an inherently ehiral O-bridged thiacallx [ 4 ] crown earboxylic acid and its application to a chiral solvating agent[ J]. Tetrahedron,2004,60(36) :7827 - 7833.
  • 5Iki N, Morohashi N, Nanmfi F, et al. Novel molecular receptors based on a thiacalix[4] arene platform. Preparations of the di- and tetra-carboxylie acid derivatives and their binding properties towards transition metalions [J]. Tetrahedron Letters, 1999,40(41) :7337 -7341.
  • 6Yang F, Zhao X, Huang C Y, Guo H Y. Synthesis and complexation properties of novel bisealixarene containing calix [ 4 ] arene and thiacalix [ 4 ] arene units [ J ]. Chin Chem Lett ,2006 ,17 (8) : 1029 - 1032.
  • 7Nabeshima T, Saiki T, Sumitomo K. Doubly bridged biscalix [ 4 ] arene for homotropic and heterotropic allosteric effects on ion recognition [ J ]. Tetrahedron Letters ,2004 ,45 (24) : 4719 - 4722.
  • 8Tantrakarn K, Ratanatawanate C, Pinsuk T. Synthesis of redox-active biscalix [4] quinones and their electrochemical properties [ J ]. Tetrahedron Letters, 2003,44 (1) :33 -36.
  • 9Bhalla V, Kumar M, Katagiri H, et al. Synthesis and binding studies of novel bisthiacalix [ 4 ] arenes with diiminme linkages [ J ]. Tetrahedron Lett, 2005,46 (1) :121 -124.
  • 10褚惠虹,王谨,潘志刚,胡晓钧,顾金英,施宪法.硫杂杯芳烃及其衍生物的合成与表征[J].有机化学,2003,23(11):1255-1259. 被引量：13

引证文献1

合成化学
2008年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部