摘要
对γ相和α相三氧化二铁纳米微晶的系列样品进行了X射线衍射(XRD)实验研究,从所得晶粒度和微结构参数发现:此纳米微晶的晶粒组元中存在着晶格畸变;随着温度的升高,γ相和α相纳米微的微结构与晶粒度和温度有着较密切的关联.对此畸变,我们给出了初步的物理解释.
We conduct an investigation into XRD (X-Ray Diffraction)microstructures on a series of nanocrystalline γ-Fe 2O 3 and α-Fe 2O 3 samples.From the obtained sizes of crystalline grains and XRD microstructural parameters,we find some patterns as follows:there exists distortion of crystal lattice in crystalline grain component of nanocrystalline Fe 2O 3;with increase in temperature the distortion of crystal lattice has relative correlation with temperature and size of cystalline grain.We give out elemetary physical explaination to the distortion of crystal lattice.
基金
国家自然科学基金
关键词
纳米微晶
XRD
微结构
晶格畸变
表面效应
氧化铁
nanocrystalline Fe 2O 3
XRD Microstructure
distortion of crystal lattice
facial effect