摘要
A Cao-Mgo-Al2O3-SiO2 quaternary system was established with the main crystal phase design based on Diopside, and the effect of once-through sintering heat treatment on microstructure of iron railings glass ceramics was studied by using DTA, SEM along with measurement of microhardness and volume density. The experimental results show that, when the total amount of FeO and Fe2O3 exceeds 10wt%, a large number of fine nuclei are produced in the annealing process, and the phenomenon of nucleus resorption happens during the process of nucleation heat treatment, which is unfavorable for preparing iron tailings glass ceramics through once-through sintering method. When the annealing temperature from 1250 ℃ to 830 ℃, setting crystallization time for 4h, without heat treatment, crystals are well grown with arrangement and interlocking in glass phase. At 830 ℃ the crystals are well developed, well distributed and of good size; with crystallization time of 4 h the crystals with radial shape have high content and regular arrangement.
A Cao-Mgo-Al2O3-SiO2 quaternary system was established with the main crystal phase design based on Diopside, and the effect of once-through sintering heat treatment on microstructure of iron railings glass ceramics was studied by using DTA, SEM along with measurement of microhardness and volume density. The experimental results show that, when the total amount of FeO and Fe2O3 exceeds 10wt%, a large number of fine nuclei are produced in the annealing process, and the phenomenon of nucleus resorption happens during the process of nucleation heat treatment, which is unfavorable for preparing iron tailings glass ceramics through once-through sintering method. When the annealing temperature from 1250 ℃ to 830 ℃, setting crystallization time for 4h, without heat treatment, crystals are well grown with arrangement and interlocking in glass phase. At 830 ℃ the crystals are well developed, well distributed and of good size; with crystallization time of 4 h the crystals with radial shape have high content and regular arrangement.
基金
Funded by State Administration of Foreign Experts Affairs and the Younger Natural Science Foundation of Liaoning(wzj-2002, 2005229001)
