摘要
Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2) nm,β=90.309(3)°,V=2.531 8(6) nm3,Z=4.In the structure,each Mn3+ and Na+ ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+ and Na+ ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.
Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets. A three dimensional heteronuclear Mn-Na compound [MnNa（N3）4（C5H5N）4] was obtained by reaction of [Mn3O（O2CCH3）6（py）3]ClO4 and NaN3 in pyridine solvents. The title compound crystallizes in monoclinic space group C2/c, a=1.536 6（2）, b=1.045 3（2）, c=1.576 3（2） nm, β=90.309（3）°, V=2.531 8（6） nm^3, Z=4. In the structure, each Mn^3＋ and Na^＋ ion coordinated with four N atoms from four N3^- and two N atoms from two pyridine molecules. Each pair of Mn^3＋ and Na^＋ ion are linked by N3^- bridges into a 3D polymer with PtS topology. CCDC： 706250.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2008年第12期2043-2046,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省自然科学基金(No.BK2006044)
江苏省教育厅重大基金(No.06KJA43014)资助项目。
关键词
异核配合物
叠氮酸根
合成
拓扑
heteronuclear complex
azido
synthesis
topology
