摘要
With the values of parameters obtained from improved ligand-field theory,by taking into account all theirreducible representations and their components in EPI as well as all the levels and the admixtures of basic wavefunc-tions within d^3 electronic configuration,the R-line thermal broadenings(TB)of both MgO:Cr^(3+)and MgO:V^(2+)havemicroscopic-theoretically been calculated.The results are in very good agreement with the experimental data.It is foundthat the R-line TB of MgO:Cr^(3+)or MgO:V^(2+)comes from the first-order term of EPI.The elastic Raman scattering ofacoustic phonons plays a dominant role in R-line TB of MgO:Cr^(3+)or MgO:V^(2+).
With the values of parameters obtained from improved ligand-field theory, by taking into account all the irreducible representations and their components in EPI as well as all the levels and the admixtures of basic wavefunctions within d^3 electronic configuration, the R-line thermal broadenings （TB） of both MgO：Cr^3＋ and MgO：V^2＋ have microscopic-theoretically been calculated, The results are in very good agreement with the experimental data. It is found that the R-line TB of MgO：Cr^3＋ or MgO：V^2＋ comes from the first-order term of EPI. The elastic Raman scattering of acoustic phonons plays a dominant role in R-line TB of MgO：Cr^3＋ or MgO：V^2＋.
基金
supported partially by National Natural Science Foundation of China under Grant No.40841012
关键词
配合基理论
电子声子交互作用
热加量
弹性黎曼散射
improved ligand-field theory, electron-phonon interaction, R line, thermal broadening, elastic Raman scattering
