摘要
固体汞膜电极具有灵敏度高,背景电流小,测定浓度范围宽等优点,连续记录16个图形最大相对误差在4%以内,电极工作一个月以后,又连续记录14个图形,最大相对误差在3.5%.电极的稳定性较好.选择适当的底液后,能获得良好的测定结果,因此汞膜电极是可以用来代替滴汞电极极谱测定铅.
The electrode of solid mercury membrane is favourably characterized with high sensitivity. low back-ground current, wide scope of determined consistency. The maximum relative error of 16 continuously recorded figures is within 4%. With the electrade having workeed for one month, 14 figures is continuously recorded again, obtuining a maximmum relative error of 3 5% that indicates beffer electrode stability. While a proper bottom liguid being selected, a fine fested result is expected to arrive at the conclusion that there is a fedsibility to determine the lead in place of the polarogram of drop mercury.
关键词
固体汞膜电极
测定
铅
稳定性
矿石
Solid mercury membrane, Lead, Determination, Stability