摘要
Mg-Cu-Y-Zn bulk metallic glasses(BMG) and in situ bulk metallic glass matrix composites were prepared by copper mold casting under the low vacuum with the argon atmosphere,and the raw materials used in preparing the Mg-Cu-Y-Zn alloys were commercially pure materials.The microstructures of the bulk samples were analyzed by X-ray diffractometer(XRD) and the thermal stability of samples was investigated by using a differential scanning calorimeter(DSC).The thermal stability of sample prepared with commercially pure raw materials is close to that of sample prepared with the high pure raw materials for the BMG Mg_(65+X)(Cu_(0.66)Y_(0.33))_(30-X)Zn_5(X=6).With the increase of Mg content,Mg-Cu-Y-Zn composites are prepared,in which Mg solid solution flakes and Y_2O_3 flakes are dispersed.In comparison with monolithic Mg-based BMG alloys,the composites exhibit significant improvement in mechanical properties,e.g.a compressive plastic strain about 7%and an ultimate strength of 1 170 MPa in Mg_(65+X)(Cu_(0.66)Y_(0.33))_(30-X)Zn_5(X=14).It is suggested that the enhancement of the mechanical properties of the composites can be attributed to the generation of multiple shear bands and the quantity of the Mg solid solution flakes.
Mg-Cu-Y-Zn bulk metallic glasses (BMG) and in siva bulk metallic glass matrix composites were prepared by copper mold casting under the low vacuum with the argon atmosphere, and the raw materials used in preparing the Mg-Cu-Y-Zn alloys were commercially pure materials. The microstructures of the bulk samples were analyzed by X-ray diffractometer (XRD) and the thermal stability of samples was investigated by using a differential scanning calorimeter (DSC). The thermal stability of sample prepared with commercially pure raw materials is close to that of sample prepared with the high pure raw materials for the BMG Mg65+x(Cu0.66Y0.33)30 xZn5 (X=6). With the increase of Mg content, Mg-Cu-Y-Zn composites are prepared, in which Mg solid solution flakes and Y2O3 flakes are dispersed. In comparison with monolithic Mg-based BMG alloys, the composites exhibit significant improvement in mechanical properties, e.g, a compressive plastic strain about 7% and an ultimate strength of 1 170 MPa in Mg65+x(Cu0.66Y0.33)30-xZn5 (X=14). It is suggested that the enhancement of the mechanical properties of the composites can be attributed to the generation of multiple shear bands and the quantity of the Mg solid solution flakes.
出处
《中国有色金属学会会刊:英文版》
CSCD
2008年第A01期278-282,共5页
Transactions of Nonferrous Metals Society of China
基金
Project(2007CB613704)supported by the National Basic Research Program of China
Project(50725413)supported by the NationalNatural Science Foundation of China
Project(CSTS2006BB4199)supported by the Project of CQ CSTC and the State Key Laboratory ofMetastable Materials Science and Technology,Yanshan University,China
关键词
Mg-Cu-Y-Zn合金
微观组织
金属材料
力学性能
bulk amorphous alloys
magnesium
commercially pure raw materials
microstructure
mechanical property