二(1,4-二噻英)-二苯含硫四氮杂卟啉铁及其磺化衍生物的合成与表征

Synthesis and Characterization of Iron(Ⅱ)1,4-Dithin-Diphenyl-Porphyrazine and Sulfonation Derivatives

为寻求更高效的光催化剂,以1,3-二亚氨基异吲哚啉和2,3-二氰基-1,4-二噻英为原料,钼酸铵为催化剂,七水合硫酸亚铁为模板,用固相法合成了二(1,4-二噻英)-二苯基四氮杂卟啉铁(FePzPh(dtn)4),并对其进行了磺化改性(FePzSPh(dtn)4).2种产物的结构经过UV-Vis、IR、1H-NMR、X-射线光电子能谱(XPS)表征,并初步探讨了其溶解性能.

To find highly efficient photocatalysis materials, complex iron （ Ⅱ ） 1,4-dithiin-diphenyl porphyrazine （FePzPh（dtn）4） and its sulfonation derivatives （FePzSPh（dtn）4） were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method using ammonium molybdate as a catalyst in the presence of ferrous sulfate heptahydrate. Their structures were characterized by UV-vis, FT-IR,^1H-NMR and X-ray photoemission spectra and their solubility properties were investigated roughly.