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温敏性金属酞菁聚合物的制备及光活性 被引量：2

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摘要 对氨基锌酞菁进行改性,并将其以共价键接枝到聚N-异丙基丙烯酰胺分子链上,制得一种新型的既有温敏性又有光活性的锌酞菁聚合物.与小分子氨基锌酞菁相比,所合成的锌酞菁聚合物能溶解于大多数有机溶剂和水,而且,在水溶液中表现出良好的温敏性,其低临界溶解温度为34.1℃.通过锌酞菁聚合物对单线态氧捕捉剂1,3-二苯基苯并呋喃的光催化降解测试,结果表明在可见光照射下,锌酞菁聚合物无论在溶解状态还是沉淀状态都具有较高的光活性.基于这些特殊性能,这种锌酞菁温敏聚合物作为一种新型光敏剂,有望在光动力学治疗领域得到广泛的应用.
作者 陈文兴 刘凡 吕汪洋 申晓媛 姚玉元 徐敏虹
机构地区 先进纺织材料与制备技术教育部重点实验室
出处 《中国科学（B辑）》 CSCD 北大核心 2008年第5期441-448,共8页 Science in China(Series B)
基金 国家自然科学基金(批准号:20574061) 教育部“新世纪优秀人才支持计划”(批准号:NCET-04-0559) 教育部“长江学者与创新团队发展计划”(批准号:IRT0654)资助
关键词 锌酞菁 温敏聚合物 光活性 单线态氧
分类号 O631.3 [理学—高分子化学]
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二级参考文献11

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共引文献7

同被引文献28

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中国科学（B辑）
2008年 第5期

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