摘要
According to the reaction of [Fe (CO)2C5H5]2 with sodium amalgam (Na/Hg), the molecular structures of crystals and the IR data of L3SnFe (CO)2C5H5 (L=C6H11, C6H5),[ (C5Me5)2Ln (CO)2FeC5H5]2(Ln=Dy, Gd, Sm, Nd, Pr) complexes, the process of forma tion of (Na[Fe (CO)2C5H5]2)n, its structure changes and reaction regularities in the synthe ses of heteronuclear metal complexes were analyzed and discussed.
According to the reaction of [Fe (CO)2C5H5]2 with sodium amalgam (Na/Hg), the molecular structures of crystals and the IR data of L3SnFe (CO)2C5H5 (L=C6H11, C6H5),[ (C5Me5)2Ln (CO)2FeC5H5]2(Ln=Dy, Gd, Sm, Nd, Pr) complexes, the process of forma tion of (Na[Fe (CO)2C5H5]2)n, its structure changes and reaction regularities in the synthe ses of heteronuclear metal complexes were analyzed and discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第1期21-23,共3页
Chemical Journal of Chinese Universities
基金
黑龙江省自然科学基金
关键词
多聚
双环戊二烯基
二羰基
铁钠
异核金属配合物
Polybis(cyclopentadienyldicarbonyliron)sodium, Reaction regularity, Heteronu clear metal complex
