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PFOS类持久性有机污染物的检测技术研究进展 被引量:10

Research Development of the Detecting Technology of PFOS and Related Persistent Contamination
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摘要 全氟辛烷磺酰基化合物(PFOS)具有很高的生物蓄积性和多种毒性,是目前最难降解的持久性有机污染物。全氟化合物独特的拒水拒油性,使其被广泛地应用于纺织、皮革、造纸等行业。由其造成的污染已经逐渐成为全球性的环境问题,随着欧盟等组织出台的关于对PFOS等物质禁令的颁布,这已经成为持久性有机污染物研究的又一热点,其分析检测技术和方法的相关研究也得到日益广泛的关注和重视。讨论了PFOS及相关全氟化合物的概况及其检测技术的研究进展,对当前各类检测技术存在的问题作了探讨。 As having highly bioaccumulation and variety of toxicity, the perfluorooctane sulfonate (PFOS) and the related perfluorine compounds were the persistent organic pollutants, which were the most difficult to degraded so far. They are water and oil repellent and have employed as surfactants and surface protectors for fabric, paper, leather and a range of applications. The contamination caused by them had gradually become a globle enviroment problem. Scientists in many countries have put much more emphasis on the research of PFOS and the related compounds as many bans are promulgated by the European Union and other international organizations. It is of great importance to develop an effective method for trace level analysis. The sample pre - treatment methods and detection technology are discussed, and the recent advances and present problems in the study of PFOS are reviewed, as well as the developing trend in research of PFOS and the related compounds.
作者 陈红梅
出处 《有机氟工业》 CAS 2008年第4期53-58,共6页 Organo-Fluorine Industry
关键词 PFOS 全氟化合物 检测 预处理 色谱法 PFOS PFCs detect pretreatment chromatogram
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参考文献31

  • 1OECD (2002) Cooperation on existing chemicals - Hazard assessment of perfluorooctane sulfonate and its saltS, environment directorate joint meeting of the chemicals committe and the working party on chemicals, pesticides and biothechnology, organisatian for economic cooperation and development, Paris, 21 November 2002.
  • 2Shoeib M, Harner T, Wilford B H, et al. Perfluorinated sulfonamides in indoor and outdoor air and indoor dust: occurrence, partitioning, and human exposure [ J ]. Environ Sci Technol,2005 , 39(17) :6599-6606.
  • 3EU. Proposal for a Directive of the european parliament and of the council relating to restrictions on the marketing and use of perfluorooctane sulfonates ( amendment of council directive 76/769/EEC) .
  • 4王立,汪正范,牟世芳,等.色谱分析样品技术[M].化学工业出版社,第二版,2002:84-87.
  • 5Hisao Hori, Etsuko Hayakawa, Nobuyoshi Yamashita, et al. High - performance liquid chromatography with conductimetrie detection of perfluorocarboxylic acids and perfluorosulfon- ates[ J]. Chemosphere, 2004,57,273 - 282.
  • 6Chiao- Li Tseng , Li- Lian Liu , Chien- Min Chenc, et al. Analysis of perfluorooctanesulfonate and related fluoro-chemieals in water and biological tissue samples by liquid chromatography - ion trap mass spectrometry [ J ]. Journal of Chromatography A, 2006.1105.119 - 126.
  • 7Xiaoli Zhao, Jidong Li, Yali Shi,et al. Determination of perfluorinated compounds in wastewater and river water samples by mixed hemimicelle - based solid - phase extraction before liquid chromatography - electrospray tandem mass spectrometry detection [ J ]. Journal of Chromatography A, 2007,1154,52 - 59.
  • 8Hansen, K.J. , Clemen, L.A. , Ellefson, M. E., Johnson, H. O. , Compound -specific, quantitative characterization of organic fluorochemicals in biological matrices [ J ]. Environ. Sci Technol,2001,35 (4) :766 - 770.
  • 9Anna Kal rrman, Bert van Bavel, Ulf Jal rnberg, et. al. Development of a Solid - Phase Extraction - HPLC/Single Quadrupole MS Method for Quantification of Perfluoro - Chemicals in Whole Blood[J]. Anal Chem, 2005, 77:864 - 870.
  • 10Horst Fr. Schr oder , Roland J. W. Meesters, Stability of fluorinated surfactants in advanced oxidation processes - A follow up of degradation products using flow injection - mass spectrometry, liquid chromatography - mass Spectrometry and liquid chromatography - multiple stage mass spectrometry[ J]. Journal of Chromatography A, 2005,1082 , 110-119.

二级参考文献40

  • 1Blake D K, Robert D H, Craig S C. Fluorinated Organics in the Biosphere[J]. Environ. Sci. Technol., 1997,31(9):2445-2454.?A
  • 2Hansen K J, Clemen L A, Ellefson M E. Compound-specific Quantitative characterization of organic fluorochemicals in biological matrices[J]. Environ. Sci. Technol., 2001,35(4):766-770.?A
  • 3Hansen K J,Johnson H O, Eldridge J S, Butenhoff J L, Dick L A.Quantitive C Characterization of Trace Levels of PFOS and PFOA in the Tennesse River[ J ]. Environ Sci Technol,2002,36 (8) : 1681-1685.
  • 4Key B D, Howell R D, Criddle C S. Fluorinated organics in the biosphere[Jl. Environ Sci Technol, 1997,31 (9) :2445-2454.
  • 5Moody C A, Martin C W, Kwan WC, et al. Monitoring perfluorinated surfactants in biota and surface water samplers following an accidental release of fire fighting foam into Etobicoke Creek [ J ]. Environ Sci Technol , 2002,36 (4), 545-551.
  • 6Gilliland F D, Mandel J S. Mortality among employees of a perfluorooctanoic acid production plant [ J ]. J Occup Med. 1993,35 ( 9 ) :950-954.
  • 7Stankov A A, Wallace K B. Structural determinants of fluorochemical induced mitochondrial dysfunction [ J ]. Toxicol Sci , 2002, 66 ( 2 ) :244-252.
  • 8Berthianme J, Wallace K B. Perfluorooctanoate perflourooctane sulfonate and N-ethyler fluorooctane sulfonamido ethanol; peroxisome proliferation and mitochondrial biogenesis[J]. Toxicol Lett,2002, 129(122) :23-32.
  • 9Case M T, York R G, Christian M S. Rat and rabbit oral developmental toxicology studies with two perfluorinated compounds [ J ]. Int J Toxicol,2001,20 (2) : 101-109.
  • 10Kannan K, Carsolini S, Palandysz l, et al. Perfluorooetanesulfonate and related fluorinated hydrocarbons in marine mammals, fishes, and birds from coasts of the Baltic and the Meditarranean seas[J]. Environ Sci Technol,2002,36 (15):3210-3218.

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