Comparison of room-temperature multiferroics in Bi_4Fe_2TiO_(12) film and bulk
Comparison of room-temperature multiferroics in Bi_4Fe_2TiO_(12) film and bulk
摘要
It was reported that both dielectricity and magnetism at room temperature were appreciably improved in Bi4Fe2TiO12 film compared with Bi4Fe2TiO12 bulk. X-ray diffraction profiles reveal similar crystalline nature and random orientation of the two, but X-ray photoelectron spectroscopy (XPS) experiments indicate that it is 1.4 eV lower binding energy of core-state Ols in the film relative to that of the bulk, so the improvement of multiferroics in the film is attributed to oxygen vacancies and high fraction of interface. The results have promising applications in multifunctional integrated devices.
It was reported that both dielectricity and magnetism at room temperature were appreciably improved in Bi4Fe2TiO12 film compared with Bi4Fe2TiO12 bulk. X-ray diffraction profiles reveal similar crystalline nature and random orientation of the two, but X-ray photoelectron spectroscopy (XPS) experiments indicate that it is 1.4 eV lower binding energy of core-state Ols in the film relative to that of the bulk, so the improvement of multiferroics in the film is attributed to oxygen vacancies and high fraction of interface. The results have promising applications in multifunctional integrated devices.
参考文献10
-
1J. Lu,L.J. Qiao,X.Q. Ma, et al.Magnetodielectric effect of Bi6Fe2Ti3O18 film under an ultra-low magnetic field[].Journal of Physics Condensed Matter.2006
-
2F. Kubel,H. Schmid.X-ray room temperature structure from single crystal data, powder diffraction measurements and optical studies of the Aurivillius phase Bi5(Ti3Fe)O15[].Ferroelectrics.1992
-
3W. Weiss,H.D. Wiemhofer,W. Gopel.Role of ionic defects at semiconductor-insulator interfaces: spectro-scopic results on CaF2/InP(001) and SrF2/InP(001) structures[].Physical Review B Condensed Matter and Materials Physics.1992
-
4R. Cavicchi,M. Tartov,S. Semancik.Preparation of well-ordered and oxygen-rich SnO2 (110) surfaces via oxygen plasma treatment[].Journal of Vacuum Science and Technology.1990
-
5J. Petzelt,P. Kuzel,I. Rychetsky, et al.Dielectric response of soft modes in ferroelectric thin films[].Ferroelectrics.2003
-
6A.Q. Jiang,L.D. Zhang.Asymmetric polarization of defect dipoles in Bi4Ti3O12 and Bi2Ti4O11 ceramics with Na+ and La3+ modifications[].Physical Review B Condensed Matter and Materials Physics.1999
-
7HUR N,PARK S,SHARMA P A,et al.Electric polarization reversal and memory in a multiferroic material induced by magnetic fields[].Nature.2004
-
8Goto T,Ki mura T,Lawes G,et al.Ferroelectricity and gi-ant magnetocapacitance in perovskite rare-earth manganites[].Physical Review Letters.2004
-
9Hemberger J H,Lunkenheimer P,Fichtl R,et al.Relaxor ferroelectricity and colossal magnetocapacitive coupling in ferromagnetic CdCr2S4[].Nature.2005
-
10A. Subramanian,Tao He,Jiazhong Chen,Nyrissa S, Rogado,,Thomas G. Calvarese."[].Advanced Materials.2006