摘要
Decomposition of dimethyl sulfide (DMS) in air was investigated experimentally by using a wire-cylinder dielectric barrier discharge (DBD) reactor at room temperature and atmospheric pressure.A new type of high pulse voltage source with a thyratron switch and a Blumlein pulse-forming network (BPFN) was adopted in our experiments.The maximum power output of the pulse voltage source and the maximum peak voltage were 1kW and 100kV,respectively.The important parameters affecting odor decomposition,including peak voltage,pulse frequency,gas flow rate,initial concentration,and humidity,which influenced the removal efficiency,were investigated.The results showed that DMS could be treated effectively and almost a 100% removal efficiency was achieved at the conditions with an initial concentration of 832mg/m3 and a gas flow rate of 1000ml/min.Humidity boosts the removal efficiency and improves the energy yield (EY) greatly.The EY of 832mg/m3 DMS was 2.87mg/kJ when the relative humidity was above 30%.In the case of DMS removal,the ozone and nitrogen oxides were observed in the exhaust gas.The carbon and sulfur elements of DMS were mainly converted to carbon dioxide,carbon monoxide and sulfur dioxide.Moreover,sulfur was discovered in the reactor.According to the results,the optimization design for the reactor and the matching of high pulse voltage source can be reckoned.
Decomposition of dimethyl sulfide （DMS） in air was investigated experimentally by using a wire-cylinder dielectric barrier discharge （DBD） reactor at room temperature and atmospheric pressure. A new type of high pulse voltage source with a thyratron switch and a Blumlein pulse-forming network （BPFN） was adopted in our experiments. The maximum power output of the pulse voltage source and the maximum peak voltage were 1 kW and 100 kV, respectively. The important parameters affecting odor decomposition, including peak voltage, pulse frequency, gas flow rate, initial concentration, and humidity, which influenced the removal efficiency, were investigated. The results showed that DMS could be treated effectively and almost a 100% removal efficiency was achieved at the conditions with an initial concentration of 832 mg/m3 and a gas flow rate of 1000 ml/min. Humidity boosts the removal efficiency and improves the energy yield （EY） greatly. The EY of 832 mg/m3 DMS was 2.87 mg/kJ when the relative humidity was above 30%. In the case of DMS removal, the ozone and nitrogen oxides were observed in the exhaust gas. The carbon and sulfur elements of DMS were mainly converted to carbon dioxide, carbon monoxide and sulfur dioxide. Moreover, sulfur was discovered in the reactor. According to the results, the optimization design for the reactor and the matching of high pulse voltage source can be reckoned.
基金
Project(No.20576121)supported by the National Natural Science Foundation of China
关键词
烟气脱硫
脉冲电晕
非热等离体
废气处理
Pulse corona discharge, Blumlein pulse-forming network （BPFN）, Decomposition, Dimenthyl sulfide （DMS）, Specific energy density, Energy yield （EY）
