摘要
A novel nickel(Ⅱ)complex[Ni(C22H34N6)](ClO4)2 had been synthesized and characterized by elementary analysis and signal-crystal X-ray diffraction analysis.The results showed that the complex crystallizes in a triclinic system,the space group P1-with a=10.209(1),b=11.617(1),c=11.916(1),α=87.633(2),β=75.940(2)°,γ=88.501(2)°,V=1369.5(2)3,Z=2,F(000)=668,Dc=1.552g/cm3,R1=0.036,wR2=0.105.In the crystal there are two independent Ni(II)centres.Each Ni(II)ion is coordinated by four secondary nitrogen atoms from one macrocycle and two oxygen atoms from two perchlorate anions to form a distorted octahedron geometry.
A novel nickel（II） complex [ Ni （C22 H34 N6） ] （ClO4）2 had been synthesized and characterized by elementary analysis and signal-crystal X-ray diffraction analysis. The results showed that the complex crystallizes in a triclinic system, the space group P with α =10.209（1） A,b =11.617（1） A,c =11.916（1） A,α =87.633（ 2 ）A,β = 75. 940（ 2 ）°,γ=88.501 （ 2 ）° V =1369.5（ 2 ） A^3, Z = 2, F（000 ） = 668,Dc = 1. 552g/cm^3, R1 = 0.036, wR2 = 0. 105. In the crystal there are two independent Ni （II） centres. Each Ni（II）ion is coordinated by four secondary nitrogen atoms from one macrocycle and two oxygen atoms from two perchlorate anions to form a distorted octahedron geometry.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2009年第1期117-119,共3页
Chemical Research and Application
关键词
镍配合物
晶体结构
大环六胺
nickel （II） complex
crystal structure
hexaazacyclotetradecane
