摘要
The title compound was obtained by the flux method and its structure was determined. It crystallizes in monoclinic, space group P2/c with a = 11.0024(17), b = 9.2979(14), c = 14.500(2) A, β = 110.879(2)°, V = 1385.9(4) A^3, Z = 4, Mr= 908.38, F(000) = 1592, p = 19.601 mm^-1, Dc = 4.353 g/cm^3, the final R = 0.0481 and wR = 0.1257 for 2532 observed reflections with I 〉 2σ(I), The Rb3La3(BO3)4 structure can be viewed as a 3-dimensional scaffold-like framework constructed by La-O polyhedra and BO3 groups. Two Rb+ ions locate in a channel along the a direction and the rest one in a cavity.
The title compound was obtained by the flux method and its structure was determined. It crystallizes in monoclinic, space group P2/c with a = 11.0024(17), b = 9.2979(14), c = 14.500(2) A, β = 110.879(2)°, V = 1385.9(4) A^3, Z = 4, Mr= 908.38, F(000) = 1592, p = 19.601 mm^-1, Dc = 4.353 g/cm^3, the final R = 0.0481 and wR = 0.1257 for 2532 observed reflections with I 〉 2σ(I), The Rb3La3(BO3)4 structure can be viewed as a 3-dimensional scaffold-like framework constructed by La-O polyhedra and BO3 groups. Two Rb+ ions locate in a channel along the a direction and the rest one in a cavity.