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二茂铁取代的笼型八聚(二甲基硅氧基)倍半硅氧烷的合成与表征 被引量:4

Synthesis and Characterization of Ferrocenyl Substituted Octakis(dimethylsiloxy) octasilsesquioxanes
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摘要 在Karstedt催化剂的催化作用下,通过把合成的笼型八聚(二甲基硅氧基)倍半硅氧烷与乙烯基二茂铁进行氢化硅烷化反应,合成了二茂铁取代的笼型八聚(二甲基硅氧基)倍半硅氧烷,产物经红外光谱、核磁共振氢谱与硅谱等进行了表征。 Ferrocenyl substituted octakis (dimethylsiloxy)- octasilsesquioxanes (POSS 2 ) was synthesized via the hydrosilylation reaction of vinyl ferrocene with as-synthesized octakis(hydrodimethylsiloxy)octasilsesquioxane under catalysis of Karstedt' s catalyst and characterized by FTIR, ^1 H NMR and ^29 Si NMR.
出处 《化学通报》 CAS CSCD 北大核心 2009年第1期43-47,共5页 Chemistry
基金 北京自然科学基金项目(2072015) 国家863计划项目(2006AA032563)资助
关键词 笼型倍半硅氧烷 二茂铁 氢化硅烷化 合成 Silsesquioxane, Ferrocene, Hydrosilylation, Synthesis
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共引文献8

同被引文献28

  • 1黄传军,张以河,付绍云,李来风.SiO_2/环氧树脂基纳米复合材料的室温和低温力学性能[J].复合材料学报,2004,21(4):77-81. 被引量:39
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  • 3何富安,张黎明,王冠海,陈旭东,伍青,王海华.反应性多面低聚倍半硅氧烷对聚烯烃的改性研究[J].高分子通报,2006(5):45-51. 被引量:12
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  • 7Caihua Ni,Guifeng Ni, Shengwen Zhang, el al. The Pr- paration of Inorganic/Organic Hybrid Nanomaterials Con- raining Silsesquioxane and Its Reinforcement for an Epoxy Resin Network[J]. Colloid Polym Sci, 2010, 288: 469- 477.
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  • 10Liu Hongzhi,Zheng Sixun,Nie Kangming. Morphology and thermomechanical properties of organic-inorganic hybrid composites involving epoxy resin and an incompletely condensed polyhedral oligomeric silsesquioxane[J].Macromolecules,2005.5088-5097.

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