期刊文献+

氮氧自由基类有机磁体的研究与展望

Studies and Outlook of Organic Magnets Containing Free Radical of Nitroxide
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摘要 氮氧自由基因其结构优势已成为有机磁体的重要构件。从纯氮氧自由基类有机磁体和含金属的氮氧自由基类有机磁体两方面综述了氮氧自由基类有机磁体的结构、种类及发展历史。分析指出氮氧自由基类有机磁体目前存在的主要问题是转换温度Tc较低及磁构关系不明确,但由于其具有诸多的优越性能而将得到大力研发。 Owing to its structural advantage, the free radical of nitroxide has been an important component for organic magnets. In view of pure and metal-contained organic magnets, this paper reviews the species, structures and development history of organic magnets containing free radical of nitroxide. These analyses indicate that the primary problems at present are lower Curie temperature and the unclear relationship between the magnetism and the structure, but duo to its distinguishing performance, organic magnet will be well studied and developed.
出处 《材料导报》 EI CAS CSCD 北大核心 2009年第3期102-105,共4页 Materials Reports
基金 国家自然科学基金项目(50673071)
关键词 氮氧自由基 纯有机磁体 含金属的有机磁体 转换温度 磁构关系 free radical of nitroxide, pure organic magnet, metal-contained organic magnet, Curie tempera ture, the relationship between the magnetism and the structure
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  • 1Miller J S, Calabrese J C, et al.Ferromagnetic behavior of [Fe(C5Me5 )2]^+ [TCNE]^- structural and magnetic characterization of decamethylferrocenium tetracyanoethenide, [Fe-(C5Me5)2]^+ [TCNE]^- MeCN and deeamethylferrocenium pentacyanopropenlde, [Fe(C5 M-e5 ) 2]^+[Ca (CN)5)]^- [J]. J Am Chem Soc,1987,109(3):769
  • 2Makarova T, Sundqvist B, Hohen R, et al. Magnetic carbon[J]. Nature,2001,413:716
  • 3刘爽,孙维林,何冰晶,林彩萍,沈之荃.有机磁体——新世纪的新材料[J].高分子通报,2004(4):1-9. 被引量:5
  • 4李承辉,顾志国,左景林,游效曾.一价金的氮氧自由基配合物的合成、结构及其磁性(英文)[J].无机化学学报,2007,23(9):1582-1586. 被引量:2
  • 5Hayakawa K, Ise T, Shiomi D, et al. Stable iiminonitroxide biradicals:building blocks for organic heterospin, heteromolecular complexes[J]. Polyhedron, 2007,26:1885
  • 6Kanzaki Y, Shiomi D, lse T, et al. Benzyl-phenyl ether derivatives of nitronyl nitroxide triradieals as a model for single-component organic molecule-based ferrimagnetics [J]. Polyhedron, 2007,26 : 1901
  • 7Tanaka H, et al. Thymine-substituted nitronyl nitroxide biradicals as a triplet (S= 1) component for bio-inspired molecule-based magnets[J]. Polyhedron,2007,26:2230
  • 8Francisco M R, Raymond Z, Michel B, et al. Evidence for transmission of ferromagnetic interactions through hydrogen bonds in alkyne-substituted nitroxide radicals: Magnetostructural correlations and polarized neutron diffraction studies [J]. J Am Chem Soc,2000,122:1298
  • 9Christophe S, et al. Rigid nitronyl-nitroxide-labelled anchoring molecules: Syntheses, structural and magnetic investigations[J]. Tetrahedron Lett,2004,45 : 9623
  • 10袭著有,韩铁,王文新.分子磁性材料的研究进展[J].纳米科技,2006,3(3):15-19. 被引量:4

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