刚性碳棒桥联金属有机化合物的合成与性质

SYNTHESIS AND PROPERTY OF ORGANOMETALLIC COMPOUNDS BRIDGED BY RIGID CARBON RODS

刚性碳棒（直线元素碳链）Ｃｘ桥联的过渡金属有机化合物ＬｎＭＣｘＭ′Ｌ′ｎ′由于其在一维分子导体、液晶材料和非线性光学材料方面的潜在应用价值而引人注目。本文总结近年来有关ＬｎＭＣｘＭ′Ｌ′ｎ′化合物的合成、性质的研究进展。

Organometallic building blocks in which linear elemental carbon chains (also called carbon rod) span two transition metals, LnMCxM′L′n′ are of interest in the development of new molecular electronics and material science. Recent advances in this exciting field was briefly summarized.