摘要
四川白皎无烟煤对碘和溴的吸附特征徐龙君刘成伦鲜学福张代钧(重庆大学资源及环境工程学院重庆400044)关键词煤,吸附,碘,溴,动力学方程碘是煤液化的有效催化剂,煤也能吸附一定量的碘,因而使得人们对煤吸附碘的研究产生了浓厚的兴趣[1~4]。以往的研究...
Adsorption characteristics of Baijiao anthracite coal to iodine and bromine have been systemically studied Adsorption of iodine on coal conforms to Freundlich experiential equation or Langmuir model The kinetics of adsorption of iodine on coal follows the unconventional first order model: q(t)=A[1exp(kt)]n Pore structure of coal adsorbed iodine in aqueous solution gets blurred The q to iodine on the demineralized coal is less than that on original coal, whereas it is larger to bromine The results obtained by desorption experiment, Xray diffraction and FTIR spectroscopy analysis show that the adsorption of iodine and bromine on coal is mainly physical process In addition, direct and alternating current conductivities of coal adsorbed iodine are about two order larger than those of the untreated coal
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
1998年第2期190-192,共3页
Journal of Fuel Chemistry and Technology
基金
国家教委博士点基金