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空气气氛下RuO_2/ZSM-5催化醇的部分氧化反应

Partial oxidation of alcohols over RuO_2/ZSM-5 catalyst in air atmosphere
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摘要 通过原位反应法制备了RuO_2/ZSM-5催化荆,并用XRD、XPS和TEM对合成的催化剂进行了表征,结果表明,RuO_2主要以20 nm左右的微晶分散在载体中,原位反应引入钌物种,没有改变载体ZSM-5的结构,大部分钌为四价。催化试验表明,在以空气为氧化剂的温和条件下,RuO_2/ZSM-5不仅可有效地催化芳香醇和带烯丙基的醇类(激活醇)氧化生成醛酮,而且对一些非激活醇也有较好的催化效果。 RuO2/ZSM-5 prepared by in-situ reaction was characterized by XRD, XPS and TEM. The results indicated that there existed mainly RuO2 particles of about 20 nm dispersing in the carrier; introduction of ruthenium species did not change structure of ZSM-5 carrier; most ruthenium existed in Ru（ IV ） . RuO2/ZSM-5 were used as the catalyst for partial oxidation of alcohols in air atmosphere. The results showed that RuO2/ZSM-5 could not only catalyze partial oxidation of aromatic alcohols and allyl alcohols （ active alcohols）, but also catalyze that of inactive alcohols.
作者 钱广 朱杰 李斌
机构地区 嘉兴学院生物与化学工程学院
出处 《工业催化》 CAS 2009年第1期34-37,共4页 Industrial Catalysis
关键词 催化化学 RuO2/ZSM-5催化剂 原位反应 选择氧化 乙醇 catalytic chemistry RuO2/ZSM-5 catalyst in-situ reaction partial oxidation alcohol
分类号 O643.36 [理学—物理化学] TQ426.94 [化学工程]
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参考文献16

  • 1Choudary B M, Lakshmi Kantam M, Lakshmi Kantam P. New and ecofriendly options for the production of speciality and fine chemicals [ J ]. Catal Today, 2000,57 : 17 - 32.
  • 2Sheldon R A, Arends I W C E, Dijksman A. New developments in catalytic alcohol oxidations for fine chemicals synthesis[ J]. Catal Today,2000,57 : 157 - 166.
  • 3Hill C L,Weinstock I A. Homogeneous catalysis:on the trial of dioxygen activation [ J ]. Nature, 1997,388:332 - 333.
  • 4Kakiuehi N, Maeda Y, Uemura S. Pd ( Ⅱ )-hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air nature [ J ]. J Org Chem, 2001, 66:6620 - 6625.
  • 5Bekvall J E, Chowdhury R L, Karlsson U. Ruthenium-catalyzed aerobic oxidation of alcohols via multistep electrontransfer [ J ]. Chem Commun, 1991,473 - 475.
  • 6Wang G Z, Andreason U, Bekvall J E. Aerobic oxidation of secondary alcohols via ruthenium-catalyzed hydrogen-transfer involving a new triple catalytic-systems[ J]. Chem Commun, 1994,1037 - 1038.
  • 7Hanyu A, Takezawa E, Sakaguchi S, et al. Selective aerobic oxidation of primary alcohols catalyzed by a Ru (PPh3 )3 Cl2/ hydroquinone system[J]. Tetrahedron Lett, 1998,39:5557 - 5560.
  • 8Vocanson F, Guo Y P, Namy J L, et al. Dioxygen oxidation of alcohols and aldehydes over a cerium dioxide-ruthenium system[ J]. Syn Commun, 1998,28:2577 - 2582.
  • 9Kaneda K, Yamashita T, Kaneda T, et al. Heterogeneous oxidation of allylic and benzylic alcohols catalyzed by Ru-Al- Mg hydrotalcites in the presence of molecular oxygen [ J ]. J Org Chem, 1998,63 : 1750 - 1751.
  • 10Matsushita T, Ebitani K, Kaneda K. Highly efficient oxidation of alcohols and aromatic compounds catalysed by the Ru-Co-Al hydrotalcite in the presence of molecular oxygen [ J]. Chem Commun, 1999,265 - 266.

二级参考文献10

  • 1Conway, B.E. Electrochemical supercapacitors. New York:Kluwer Academic/Plenum Publishers, 1999
  • 2Conway, B.E.J. Electrochem. Soc., 1991, 138(6): 1539
  • 3Nan, J. M.; Yang, Y.; Lin, Z.G. Chin. J. Power Sources,1996,20(4):152[南俊民,杨勇,林祖赓.电源技术(Dianyuan Jishu), 1996, 20(4): 152]
  • 4Zheng, J.P.; Jow, T.R.J. Electrochem. Soc., 1995, 142(1): L6
  • 5Wang, X. F.; Kong, X. H.; Liu, Q. G.; Xie, J.Y. Electronic Components ＆ Materials,2000,19(5):26[王晓峰,孔祥华,刘庆国,解晶莹.电子元件与材料(Dianzi Yuangian Yu Cailiao),2000, 19(5): 26]
  • 6Liu, K. C.; Anderson, M.A.J. Electrochem. Soc., 1996,143(1): 124
  • 7Ma, R.Z.; Liang, J.; Wei, B.Q.J. Power Sources, 1999,84(1): 126
  • 8Zheng, J. P.; Cygan, P. J.; Jow, T.R.J. Electrochem.Soc., 1995, 142(8): 2699
  • 9王晓峰,孔祥华.新型氧化镍超电容器电极材料的研究[J].无机材料学报,2001,16(5):815-820. 被引量：20
  • 10闪星,张密林.纳米氧化镍在超大容量电容器中的应用[J].功能材料与器件学报,2002,8(1):35-39. 被引量：31

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工业催化
2009年 第1期

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