一种新型双核锰配合物的合成与表征

Synthesis and characterization of a new binuclear manganese (Ⅲ) complex.

合成了一种新型双核锰（Ⅲ）的配合物Ｍｎ２（ＨＬ）４ＯＡｃＨ２Ｏ，其中ＨＬ－为二齿配体水杨醛缩氨脲．运用元素分析、化合价测定、电导率、磁化率、热重分析、ＩＲ、Ｕｖ－Ｖｉｓ、ＥＳＲ等多种分析手段对其性质进行了研究，提出了配合物可能的结构式．

A new complex Mn 2(HL) 4·OAc·H 2O is synthesized and characterized by elemental analysis, valence determination, molar conductivity, eletronic magnetic susceptibility, thermoanalyses, IR, Uv Vis, ESR spectra etc. The possible structure of the complex is suggested.