摘要
综述了β-环糊精应用于液相反应研究的最新进展,对β-环糊精作为催化剂或反应载体进行开环、氧化、脱保护等反应进行分类阐述,包括对β-环糊精的反应底物选择性能和催化性能进行分析,认为β-环糊精与底物的相互作用可有效地催化液相有机化学反应,提高反应选择性。提出β-环糊精尤其是β-环糊精衍生物在有机合成反应中将具有广阔的发展前景。
The advanced study about β-cyclodextrin applied in liquid-phase reaction systems were summarized, the selective-ablity and catalytic-ability of β-cyclodextrin were analyzed, including the description about ring opening reaction systems, oxidative reaction systems and deprotected reaction systems catalyzed by fl-cyclodextrin. The interaction between β-cyclodextrin and substrates could effectively catalyze some liquid-phase organic reactions, and the selectivities could be enhanced accordingly, it was proposed that β-cyclodextrin as well as the ramifications of β-cyclodextrin would exhibit their wider application in the liquid-phase organic reactions.
出处
《广东化工》
CAS
2009年第2期38-41,共4页
Guangdong Chemical Industry
基金
国家自然科学基金资助项目(20776053)
关键词
Β-环糊精
载体
选择性
液相
催化剂
β-cyclodextrin
carrier
selectivity
liquid-phase
catalyst
