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纳米二氧化钛对纳米纤维增强透光复合材料性能的影响 被引量:1

Influence of TiO_2 Nano Particles on Properties of Nanofiber Reinforced Transparent Composites
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摘要 对纳米二氧化钛粒子改性聚甲基丙烯酸甲酯(PMMA)透光复合材料的性能进行研究。通过将二氧化钛纳米粒子分别加在同轴共纺复合纳米纤维的壳/芯结构中,分析了相同含量二氧化钛粒子在不同结构中的分布状况以及对纳米纤维增强透光复合材料透光性和紫外光吸收性的影响。研究结果表明:分布在芯层中的纳米二氧化钛粒子对纳米纤维增强透光复合材料的透光性能影响较小,且能在200-400nm^-1的紫外光区域产生明显的吸收峰。 Development of nanofiber reinforced transparent composites added with nano-titanium dioxide (TiO2) particles was made in this paper, in which poly( methyl methacrylate) (PMMA) acted as the matrix material. Applying the same amount of TiO2 particles either in core or in shell part of co-axially electrospun composite nanofibers, their distribution status in different parts and their influence on optical properties of the transparent composites such as visible light transparency and ultraviolet light absorbency was analyzed . Resuits show that the added TiO2 particles in the core part gave less influence on the visible light transparency, accompanied with an obvious absorbing peak in ultraviolet light region around wavelength of 200 - 400nm^-1.
出处 《航空材料学报》 EI CAS CSCD 北大核心 2009年第1期81-86,共6页 Journal of Aeronautical Materials
基金 国家自然科学基金(50773054)
关键词 纳米二氧化钛粒子 聚甲基丙烯酸甲酯 透光复合材料 同轴共纺 紫外光 nano-titanium dioxide ( TiO2 ) poly ( methyl methacrylate) (PMMA) transparent composite co-axial eleetrospinning ultraviolet light
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参考文献9

  • 1NUSSBAUMER Rene' J, CASERI Walter R, SMITH Paul,et al. Polymer-TiO2 nanocomposites: A route towards visually transparent broadband UV filter and high refractive index materials [ J]. Macromol. Mater. Eng, 2003, 288: 44 - 49.
  • 2LIU Xuan-yong, ZHAO Xiao-bing, LI Bao-e. UV-irradiation-induced bioaetivity on TiO2 coatings with nanostructural surface [ J]. Acta Biomaterialia, 2008, In Press.
  • 3KIM Jung-Kon, CHOI Kyungho, CHO Il-Hyoung. Application of a microbial toxicity assay for monitoring treatment effectiveness of pentachlorophenol in water using UV photolysis and TiO2 photocatalysis [ J]. Journal of Hazardous Materials. 2007, 148(2) : 281 -286.
  • 4XIAO Guang-can, WANG Xin-chen, LI Dan-zhen. InVO4- sensitized TiO2 photocatalysts for efficient air purification with visible light [ J]. Journal of Photochemistry and Photobiology (A) : Chemistry. 2007, 193 (3) : 213 - 221.
  • 5SAKANOTO Masashi, OKUDA Haruo. Influence of Particle Size of Titanium Dioxide on UV-ray Shielding Property [J]. Jap Soc Colour Mater. 1995, 168(4): 203 -206.
  • 6FURUSAWA Takeshi, HONDA Kozue, UKAJI Emi. The microwave effect on the properties of silica-coated TiO2 fine particles prepared using sol-gel method [J]. Materials Research Bulletin. 2008, 43(4) :946 -957.
  • 7XU Li-xin, YANG Mu-jie. Situ compatibilization of polypropylene and polystyrene-grafted nano-sized TiO2 in the presence of Friedel-Crafts catalyst [ J]. Materials Letters. In press.
  • 8黄争呜,张彦中.共轴复合连续纳/微米纤维及其制备方法,中国发明专利号:ZL200310108130.9.
  • 9陈卢松,黄争鸣,董国华,何创龙.PMMA透光纳米复合材料的制备[J].航空材料学报,2008,28(1):59-64. 被引量:9

二级参考文献15

  • 1CHENG Shih-kai,CHEN Chuh-yung.Mechanical properties and strain-rate effect of EVA/PMMA in situ polymerization blends[J].European Polymer Journal,2004,40:1239-1248.
  • 2OHNAGA Takashi,SATO Toshiaki,NAGATA Shiro.Miscibility and phase behaviour of methyl methacrylate copolymer and polycarbonate blends[J].Polymer,1997,38(5):1073-1079.
  • 3SCHAUER E,BERGLUND,PENA L G.Morphological variations in PMMA-modified epoxy mixtures by PEO addition[J].Polymer,2002,43:1241 -1248.
  • 4AYRE D S,BUCKNALL C B.Particle cavitation in rubbertoughened PMMA experimental testing of the energy-balance criterion[J].Polymer,1998,39 (20):4785 -4791.
  • 5NUSSBAUMER Rene J,CASERI Walter R.SMITH Paul.Polymer-TiO2 nanocomposites:A route towards visually transparent broadband UV filters and high refractive index materials[J].Macromolecular materials and engineering,2003,288(1):44 -49.
  • 6ESSADDEQ S H,ULCINELLI S H,SANTILLI C V.Microstructure and corrosion resistance of inorganic-organic(ZrO2-PMMA) hybrid coating on stainless steel[J].Journal of Non-Crystalline Solids,1999,247:164-170.
  • 7TANG Erjun,CHENG Guo-xiang,MA Xiao-lu.Preparation of nano-ZnO/PMMA composite particles via grafting of the copolymer onto the surface of zinc oxide nanoparticles[J].Powder Technology,2006,161:209-214.
  • 8OLSON J R,DAY D E,Stoffer J O.Fabrication and mechanical properties of optically transparent glass fiber/polymer matrix composites[J].Journal of Composite Materials,1992,26 (8):1181 -1193.
  • 9KUDOH H,SASUGA T,SEQUCHI T.High energy ion irradiation effects on polymer materials:2.Proton irradiation effects on PMMA and GFRP[J].Polymer,1996,37(21):4663 -4665.
  • 10SUZUKI Toshio,SAKAE Youko,KUSHIBIKI Nobuo.Preparation and properties of Inorganic-organic composite materials containing R3 SiO1/2,SiO2,and TiO2 units[J].Chem Mater,1994,6:692-696.

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